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Chemistry
Electrolysis and Electrochemistry
Electrochemistry
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Gabrielle Thomas
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Cards (27)
What is the electrochemical series of metals?
Potassium-
K
+
K^+
K
+
Calcium-
C
a
2
+
Ca^{2+}
C
a
2
+
Sodium-
N
a
+
Na^+
N
a
+
Magnesium-
M
g
2
+
Mg^{2+}
M
g
2
+
Aluminium-
A
l
3
+
Al^{3+}
A
l
3
+
Zinc-
Z
n
2
+
Zn^{2+}
Z
n
2
+
Iron-
F
e
2
+
Fe\ ^{2+}
F
e
2
+
Lead-
P
b
2
+
Pb^{2+}
P
b
2
+
Hydrogen -
H
+
H^+
H
+
Copper-
C
u
2
+
Cu^{2+}
C
u
2
+
Silver-
A
g
+
Ag^+
A
g
+
Do metals act as reducing agents or oxidising agents when they react with other substances?
Reducing
agents
What is the rule for displacement of metals in the reactivity series?
The higher the metals are in the reactivity is what will be
discharged
.
When will hydrogen be displaced?
When the reaction occurs with metals above hydrogen in the
electrochemical
series
of metals.
What are he the two types of displacement that occur with elements of the electrochemical series of metals?
Displacement of metals
Displacement of
hydrogen
What is the electrochemical
Fluorine
-
F
−
F^-
F
−
Sulfate
-
S
O
4
2
−
SO_4^{2-}
S
O
4
2
−
Nitrate
-
N
O
3
−
NO_3^-
N
O
3
−
Chlorine
-
C
l
−
Cl^-
C
l
−
Bromine
-
B
r
−
Br^-
B
r
−
Iodine
-
I
−
I^-
I
−
Hydroxide
-
O
H
−
OH^-
O
H
−
Do the non-metals act as oxidizing or reducing agents?
Oxidising
agents
What is the rule for displacement of non-metals?
A non-metal will displace a non-metal which is below it in the
electrochemical
series.
What are electrical conductors?
Substances which allow
electricity
to pass through.
What are the non- conductors?
Substances which do not allow an
electric current
to pass through
What are some general, common of conductors?(6)
Metals
Graphite
Molten
ionic compounds
Solutions of ionic compounds
Aqueous
acids
Alkalis
What are some common, general non-conductors?
Non-metals
Plastics
Covalent
Substances
Solid
ionic compounds
What is an electrolyte ?
A compound that forms
ions
when
molten
or in
aqueous
solution.
What allows metallic conduction to occur?
Mobile electrons
What allows electrolytic conduction?
Free movement of
ions
What is the difference between metallic conduction and electrolytic conduction?
Mobile ions
carry the electric current through the
electrolyte
Mobile electrons
carry the electric current through the metal
The metal remains chemically unchanged
The electrolyte decompose
What are strong electrolytes?
substances that are fully
ionised
when dissolved in water
What are weak electrolytes?
Substances that are only partially
ionised
when dissolved in water.
What are the common strong electrolyte groups?
Strong
alkalis
Strong
acids
Soluble ionic compounds
What are the common weak electrolyte groups?
Weak acid
Weak alkalis
What is some examples of Strong electrolyte acids?
Hydrochloric acid
Nitric acid
Sulfuric acid
What is some examples of weak electrolyte acids?
Carbonic acid
Ethanoic acid
What is some examples of Strong electrolyte alkalis?
Sodium hydroxide
Potassium hydroxide
What is an example of weak electrolyte alkali?
Aqueous
ammonia
What is some examples of Strong electrolyte salts ?
Molten
sodium
chloride
Sodium Chloride
Molten
potassium
bromide
Potassium bromode solution
What is a non-electrolyte?
A
substance
which remains as
molecules
when in the
liquid
state or
dissolved
in
water.
What are the key facts about pure water?
Water undergoes spontaneous
ionisation
into
H
+
H^+
H
+
ions and
O
H
−
OH^-
O
H
−
An extremely weak
electrolyte
5.56 x 10
8
^8
8
molecules are ionised at one time
The concentration of
H
+
H^+
H
+
and
O
H
−
OH^-
O
H
−
ions in pure water is
1
x
1
0
−
7
m
o
l
d
m
−
3
1\ x\ 10^{-7}moldm^{-3}
1
x
1
0
−
7
m
o
l
d
m
−
3