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Chemistry
Alcohols
Dehydration/ elimination of alcohol
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Cards (12)
What can alcohols be converted into?
Alkenes
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What reagent is used to heat alcohols under reflux for dehydration?
Concentrated sulfuric acid or phosphoric acid
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What is produced when cyclohexanol is dehydrated?
Cyclohexene
and water
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What does dehydration of alcohols produce?
A
water molecule
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What type of reaction is the dehydration of alcohols?
Elimination reaction
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What is removed in the dehydration of alcohols?
A small molecule,
water
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What alkenes can be formed from pentane-2-ol?
Pent-1-ene
and
pent-2-ene
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What is the first step in the dehydration mechanism of alcohols?
Lone pair
on
oxygen
attracts hydrogen ion
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What happens after the oxygen forms a bond with the hydrogen ion?
An
intermediate molecule
with positive oxygen forms
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What occurs to the electrons during the dehydration reaction?
They move to form water and
alkene
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What is regenerated at the end of the dehydration reaction?
The
acid catalyst
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What is the dehydration mechanism of alcohols using a concentrated acid catalyst?
Lone pair
on oxygen attracts hydrogen ion.
Covalent bond
forms with hydrogen ion.
Intermediate with positive oxygen is created.
Electrons move to release water.
Electrons between carbon and hydrogen shift.
Alkene and water are produced,
regenerating
the acid.
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