redox stands for reduction and oxidation reactions
redox reactions involve the transfer of e- (electrons)
redox reaction is comprised of two half equations:
oxidation: loss of electrons (OIL)
reactant of this reaction = reductant
what are redox reactions?
redox stands for reduction and oxidation reactions
redox reactions involve the transfer of e- (electrons)
redox reaction is comprised of two half equations:
oxidation: loss of electrons (OIL)
reactant of this reaction = reductant
reduction: gain of electrons (RIG)
reactant of this reaction = oxidant
what are the oxidation number rules?
The oxidation number of an element in its elemental form is zero. 2. The sum of oxidation numbers = overall charge
3. for ions, the oxidation number = charge e.g. Na+ = +1
4. Oxygen usually has an oxidation number of -2, unless it is in a peroxide where it is -1. (H2O2)
5. Hydrogen usually has an oxidation number of +1, unless it is in a hydride where it is -1.
how to identify reduction and oxidation reactions?
oxidation reaction: reducant's (reactant) oxidation number will increase
reduction reaction: oxidant's (reactant) oxidation number will decrease
steps:
identify conjugate pairs
identify oxidation + reduction reaction (oxidation number increase or decrease)
label reductant + oxidant
what are the steps to write half equation in acidic conditions (acidic is implied unless mentioned otherwise?
KOHES
key elements (not oxygen or hydrogen)
Oxygen (+H2O)
hydrogen (+H+)
electrons (e-) -> balance charge
states
what are the steps to write half equations in basic/alkaline conditions?
KOHES
nH+ -> add nOH- to BOTH SIDES
nH+(aq) + nOH-(aq) -> nH2O(l)
cancel down H2O
how to go from full equations to half equations?
identify oxidant and reductant reactants and their conjugates using oxidation numbers (ignore H2O or H+)