A fractionating column contains glass beads, which act as surfaces on which vapour leaving the column can condense, then be evaporated again as more hot vapour passes up the column.
The vapour in a fractional distillation column undergoes several repeated distillations as it passes up the column, permitting better separation of the fractions.
One advantage of fractionaldistillation is that it can be used when there is minimal difference in boiling temperatures between compounds.
Fractionaldistillation has a similar set up to simpledistillation, but has a fractionating column between the heatingflask and still head.
One disadvantage of fractional distillation is that it takes longer than simple distillation.