Assuming the list order has been randomised, this method offers an unbiased chance of gaining a representative sample, making the results easier to generalise to the population
The target population is divided into sub-sets e.g. age, gender, class etc. and a random sample is taken from these sub-sets. This ensures that the sample is representative of the population.
Those who respond to the call for volunteers may all display similar characteristics thus increasing the chances of yielding an unrepresentative sample, making the results harder to generalise to the population