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Topic 12: Acid-Base Equilibria
12.4 Acid Dissociation Constant (Ka)
12.4.1 Expression for Ka
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The Ka value for a weak acid with equilibrium concentrations [H+] = [A-] = 0.01 M and [HA] = 0.09 M is
0.0011
Weak acids dissociate completely in solution.
False
Steps in the dissociation of a weak acid in water:
1️⃣ HA partially dissociates
2️⃣ Forms H+ and A-
3️⃣ Forward and reverse reactions reach equilibrium
The general dissociation equation for a weak acid HA in water is HA(aq) ⇌ H⁺(aq) +
A⁻(aq)
An example of a strong acid is
hydrochloric
acid.
What type of dissociation do weak acids undergo in solution?
Partial dissociation
An example of a weak acid is
acetic
acid.
The dissociation of a weak acid in water results in
equilibrium
.
The dissociation equation for a weak acid HA in water is HA(aq) ⇌
H⁺
(aq) + A⁻(aq).
Write the dissociation equation for acetic acid (CH₃COOH) in water.
CH₃COOH(aq) ⇌ H⁺(aq) + CH₃COO⁻(aq)
Weak acids partially dissociate to form hydrogen ions and their
conjugate base
.
The expression for Ka is Ka =
[H⁺][A⁻]
/[HA].
A higher Ka value indicates a
stronger
weak acid.
Match the term with its definition:
[H⁺] ↔️ Concentration of hydrogen ions
[A⁻] ↔️ Concentration of conjugate base
[HA] ↔️ Concentration of undissociated acid
What does a higher Ka value indicate about a weak acid?
Stronger weak acid
The acid dissociation constant is denoted as
Ka
A higher Ka value means the
acid
dissociates more readily in water.
What are the two key steps to calculate Ka?
Determine equilibrium concentrations and plug into the Ka expression
The Ka quantifies the ratio of products to reactants at
equilibrium
The acid dissociation constant (Ka) measures the extent to which a weak acid dissociates in
solution
A higher Ka value indicates a
stronger
weak acid.
What is the expression for Ka in terms of equilibrium concentrations?
Ka = \frac{[H^+][A^-]}{[HA]}</latex>
[H+] refers to the concentration of hydrogen
ions
Match the term with its definition:
[H+] ↔️ Concentration of hydrogen ions
[A-] ↔️ Concentration of conjugate base
[HA] ↔️ Concentration of undissociated weak acid
What is the Ka value if [H+] = 0.01 M, [A-] = 0.01 M, and [HA] = 0.09 M?
0.0011
The acid dissociation constant is denoted as
Ka
What does the term Ka quantify in the context of acid dissociation?
Ratio of products to reactants
A higher Ka value indicates that the weak acid dissociates more
readily
in water.
Steps to calculate the acid dissociation constant (Ka) for a weak acid:
1️⃣ Determine the equilibrium concentrations of H+, A-, and HA.
2️⃣ Plug these values into the Ka expression.
3️⃣ Solve for Ka.
What is the Ka value if [H+] = 0.01 M, [A-] = 0.01 M, and [HA] = 0.09 M?
0.0011