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Topic 8: Energetics I
8.1 Enthalpy Changes
8.1.1 Standard Enthalpy Changes
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What is the standard enthalpy change (ΔH°)?
Change in enthalpy under standard conditions
The standard enthalpy change is measured under standard conditions, which include a temperature of
298
K and a pressure of 1 atm.
The standard enthalpy change is expressed in
kJ/mol
.
What is the standard enthalpy of formation (ΔH°f)?
Enthalpy change when 1 mole of a compound is formed from its elements
The standard enthalpy of combustion (ΔH°c) is the enthalpy change when 1 mole of a substance is completely burned in
oxygen
.
What does the standard enthalpy of reaction (ΔH°r) measure?
Enthalpy change for a reaction under standard conditions
Standard conditions include a temperature of298 K and a pressure of
101.3 kPa
.
Match the standard condition with its value:
Temperature ↔️ 298 K
Pressure ↔️ 1 atm
Give an example of a reaction for the standard enthalpy of formation (ΔH°f).
H₂(g) + ½ O₂(g) → H₂O(l)
What is an example of a reaction for the standard enthalpy of combustion (ΔH°c)?
CH₄(g) + 2O₂(g) → CO₂(g) + 2H₂O(l)
What is an example of a reaction for the standard enthalpy of reaction (ΔH°r)?
2H₂(g) + O₂(g) → 2H₂O(l)
Standard conditions and STP have the same temperature and pressure.
False
What is the temperature in Kelvin for STP?
273 K
The standard enthalpy of formation for water (H₂O) is -286
kJ/mol
.
What is the standard enthalpy of formation for liquid water (H₂O)?
-286 kJ/mol
Standard conditions for enthalpy changes are defined as 298 K and
1 atm
The standard temperature for enthalpy changes is
25°C
.
What is the key difference between standard conditions and STP in terms of temperature?
298 K vs. 273 K
The standard enthalpy of formation is the enthalpy change when 1 mole of a compound is formed from its
elements
What is the symbol for the standard enthalpy of combustion?
ΔH°c
The standard enthalpy of formation is expressed in
kJ/mol
.
The standard enthalpy of combustion is measured when 1 mole of a substance is completely burned in
oxygen
What is the standard enthalpy of combustion for methane (CH₄)?
-890 kJ/mol
The standard enthalpy of combustion is always
exothermic
.
What is the standard enthalpy of combustion for methane (CH₄)?
-890 kJ/mol
The standard enthalpy of neutralization is the enthalpy change when 1 mole of water is formed by the complete neutralization of an acid and a
base
What is the standard enthalpy of neutralization for HCl with NaOH?
-57.2 kJ/mol
The standard enthalpy of neutralization is expressed in
kJ/mol
.
The standard enthalpy change is the change in enthalpy when a reaction occurs under standard
conditions
What is the standard enthalpy change for the formation of water (H₂O)?
-286 kJ/mol
Match the term with its definition under standard conditions:
Temperature ↔️ 298 K (25°C)
Pressure ↔️ 1 atm (101.3 kPa)
What temperature is specified under standard conditions in Kelvin?
298 K
The standard pressure under standard conditions is
1 atm
Standard conditions and standard temperature and pressure (STP) use the same temperature.
False
What is the standard temperature in degrees Celsius under standard conditions?
25°C
Match the standard conditions with their values:
Standard Temperature ↔️ 298 K
Standard Pressure ↔️ 1 atm
What is the standard enthalpy of formation for water (H₂O) under standard conditions in kJ/mol?
-286 kJ/mol
The standard enthalpy of formation is the enthalpy change when 1 mole of a compound is formed from its
elements
in their standard states.
What is the definition of the standard enthalpy of combustion?
Complete combustion of 1 mole
Match the type of enthalpy change with its symbol:
Standard Enthalpy of Formation ↔️ ΔH°f
Standard Enthalpy of Combustion ↔️ ΔH°c
Standard Enthalpy of Neutralization ↔️ ΔH°neut
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