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Topic 2: Bonding and Structure
2.3 Metallic Bonding
2.3.1 Structure of Metals
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What is metallic bonding defined as?
Electrostatic attraction between positive ions and a sea of electrons
In metallic bonding, metal atoms lose valence electrons to become positive
ions
Delocalized electrons in metallic bonding provide
electrical conductivity
.
What is the key property of metals due to metallic bonding?
High electrical conductivity
What does the electron sea model describe?
Metallic bonding as an electrostatic attraction
In the electron sea model, the outer valence electrons of metal atoms become
delocalized
The electron sea allows metals to have high
electrical conductivity
.
Match the bonding type with its characteristics:
Ionic ↔️ Localized electron arrangement
Covalent ↔️ Shared electron pairs
Metallic ↔️ Delocalized electron sea
What is the arrangement of metal atoms in a lattice structure?
Highly ordered three-dimensional arrangement
Metal atoms in a lattice are densely packed in arrangements like FCC, BCC, or
HCP
Metals have high electrical conductivity because of
delocalized electrons
.
What is the definition of metallic bonding?
Electrostatic attraction between ions and electrons
In metallic bonding, metal atoms lose valence electrons to become positive
ions
What is the role of delocalized electrons in metallic bonding?
High electrical conductivity
The metallic lattice structure consists of a regular arrangement of
metal ions
.
The electron sea model describes metallic bonding as an electrostatic attraction between positive metal ions and a sea of delocalized
electrons
What happens to the outer valence electrons in the electron sea model?
They become delocalized
The delocalized electron sea in metals allows for high
electrical conductivity
.
Metallic bonding results in properties such as high conductivity, malleability, and
ductility
What are the key characteristics of metal lattice structures?
Ordered, 3D arrangement
Match the type of metal packing with its description:
FCC ↔️ Atoms in cube faces
BCC ↔️ Atoms in cube center
HCP ↔️ Hexagonal close-packed
Why are delocalized electrons essential for thermal conductivity in metals?
They move freely
The strong electrostatic attraction between ions and the
electron
sea maintains lattice stability.
Metal atoms are densely packed in specific arrangements like FCC, BCC, or
HCP
What is the arrangement of atoms in a metal lattice structure?
Three-dimensional ordered array
Metals are densely packed in arrangements like FCC, BCC, or
HCP
What is the role of delocalized electrons in metals?
Electrical and thermal conductivity
Strong electrostatic attraction between positive ions and delocalized electrons maintains
lattice
stability in metals.
Match the structure with its bond formers:
Metal ↔️ Positive ions & electron sea
Ionic ↔️ Positive & negative ions
Covalent ↔️ Shared electron pairs
What type of electrical conductivity do covalent compounds typically have?
Generally poor
The delocalized electrons in metals contribute to their high electrical
conductivity
What two factors contribute to the properties of metals?
Metallic lattice and delocalized electrons
Why are metals malleable and ductile?
Delocalized electrons allow ions to slide
Metals generally have low melting and boiling points compared to
ionic compounds
.