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Yr 2 Chem
Yr 2 Organic
Phenols
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A phenol is an
aromatic
compound with a
hydroxyl
group directly bonded to a
benzene
ring.
Phenols are weakly
acidic
as they partially
dissociate
in water. They react with strong bases but not weak bases.
Phenols undergo
electrophilic
substitution aqueous bromine forming a
white
precipitate of
2
,
4
,
6-tribromophenol
+
HBr
When reacted with dilute
nitric
acid at room temperature, phenols form a mixture of
2-nitrophenol
and
4-nitrophenol.
Phenols are more
reactive
than benzene due to the presence of a
lone pair
of electrons in the
oxygen p-orbital
of the
hydroxyl
group.