IUPAC - International Union of Pure and Applied Chemistry
. Names produced by IUPAC rules are called systematic names
Parent name - indicates the number of carbons in the longest continuous carbon chain in the molecule.
Suffix - this indicates what primary functional group is present.
Locant gives the location of the primary functional group.
Prefix - reveals the identity, location, and number of substituents attached to the carbon chain. The prefix also indicates the configuration of the compound being named.
Functional group refers to an atom or a group of atoms with characteristic chemical and physical properties for reactivity.
Functional groups often have atoms other than carbon or hydrogen (heteroatoms) or double bonds (π bonds) that make them distinctive. These features define one type of organic molecule from another.
These structural features can be a heteroatom – atoms other than carbon or hydrogen – or π bonds which distinguish one organic molecule from another.
Hydrocarbons: These are simple organic molecules made up of only carbon and hydrogen atoms.
Compounds with a C – Z σ Bond (Z = Electronegative Element):
This type includes molecules where carbon is bonded to another element (Z) through a single bond (σ bond). Z is usually an electronegative element, meaning it has a tendency to attract electrons. Examples are CH₃Cl (methyl chloride) where C is bonded to Cl.
Compounds with a C – Z σ Bond (Z = Electronegative Element):
This type includes molecules where carbon is bonded to another element (Z) through a single bond (σ bond). Z is usually an electronegative element, meaning it has a tendency to attract electrons.
Compounds Containing a C=O Group:These are molecules that have a carbon double-bonded to an oxygen atom, known as a C=O group.
Hydrocarbons are compounds made up of only the elements carbon and hydrogen. They may be aliphatic (straight-chain) or aromatic.
Aliphatic Hydrocarbons: These can be either straight-chain (like a simple chain) or branched-chain hydrocarbons. They include alkanes, alkenes, and alkynes.
Aromatic Hydrocarbons: Named for their characteristic odors, but not all of them have a strong smell. Aromatic hydrocarbons often contain a special ring structure called a benzene ring.
Alkanes:
Structure: Consist of carbon-carbon (C–C) single bonds.
Example: Methane (CH₄).
No additional functional groups, just straight single bonds.
Alkenes:
Structure: Contain a carbon-carbon (C–C) double bond.
Example: Ethene (C₂H₄).
The double bond is the functional group, making them more reactive than alkanes.
Alkynes:
Structure: Have a carbon-carbon (C–C) triple bond.
Example: Ethyne (C₂H₂).
The triple bond is the functional group, and alkynes are even more reactive than alkenes.
Aromatic hydrocarbons are known for their stability and often have a distinctive ring structure called a benzene ring.
Alkanes are relatively inert (less reactive), while alkenes and alkynes are more reactive due to their double and triple bonds.
Aromatic compounds, like benzene, are stable and exhibit unique reactivity patterns.
Hydrocarbons are prevalent in fuels, plastics, and various organic compounds that form the basis of living organisms.
These are smaller groups derived from straight-chain alkanes by removing one hydrogen atom. They are named by changing the -ane ending to -yl.
Branched-Chain Alkanes:
These are alkanes where the carbon chain has branches or substitutions. They are named with a prefix for the substituent, followed by the parent alkane name, and ending with -ane.
straight-chain alkanes have a continuous chain, alkyl groups are derived from alkanes by removing one hydrogen, and branched-chain alkanes have branches or substitutions on the carbon chain.