More organic

Cards (9)

  • Radicals are species with an unpaired electron which can be easily removed, therefore making them highly reactive.
  • Free radicals can be formed by homolytic fission.
  • A covalent bond between atoms in a halogen molecule can be broken in homolytic fission, which splits the pair of electrons between the two atoms forming two free radicals.
  • Cl - Cl -> Cl• + Cl•
  • Initiation is the step of free radicals substitution where diatomic halogen molecules are split into halogen free radicals by ultraviolet light.
  • Propagation is when the chain reaction occurs. The free radical abstracts hydrogen from another molecule to form a new free radical.
  • Propagation consists of two steps. First the free radicals removes an alkanes hydrogen atom forming an alkyl radical and another molecule. Next the alkyl radical gains a halogen atom to form a haloalkane and a new halogen free radical.
  • Termination of free radical substitution occurs when two free radicals react to form a stable molecule that no longer participates in the chain reaction.
  • Prefixes for organic compounds:
    • Meth
    • Eth
    • Prop
    • But
    • Pent
    • Hex
    • Hept
    • Oct
    • Non
    • Dec