Polymers are long chain molecules, made up of many smaller repeating units called monomers, which are joined together by chemical reactions.
Polymers can be natural or artificial and they are very useful.
The larger a molecule is, the stronger its intermolecular forces. This means polymers can have high melting points, despite being molecular.
Cross links are covalent bonds between polymer chains.
Cross links are covalent bonds between polymer chains.
When a polymer is not crosslinked, the chains are held together by weak intermolecular forces so they can be separated relatively easily, giving lower melting points.
When a polymer is cross-linked, strong covalent bonds hold the chains together, so it is much harder to separate. They do not melt because they would react at a lower temperature than they can melt.