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chemistry
acids and bases
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Cards (122)
What are Bronsted-Lowry acids defined as?
Proton
donors
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What do Bronsted-Lowry bases do?
They accept
protons
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What characterizes strong acids compared to weak acids?
Strong acids
dissociate
almost completely
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Name a strong base.
Sodium hydroxide
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What is the equilibrium position for weak acids?
It
lies
to
the
left
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How does the equilibrium position differ between strong and weak acids?
Strong acids favor
products
, weak acids favor
reactants
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How does temperature affect Kw
Kw changes with temperature
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What does pH measure?
The concentration of
H<sup>+</sup>
ions
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What is the formula to calculate pH?
pH = -
log<sub>10</sub>
[H<sup>+</sup>]
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If a solution has a pH of 3, what is the concentration of H<sup>+</sup> ions?
1 x 10<sup>-3</sup>
mol/dm<sup>3</sup>
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What are the key characteristics of strong and weak acids and bases?
Strong acids:
dissociate
almost completely
Weak acids: dissociate poorly
Strong bases: produce many
OH
<sup>-</sup>
ions
Weak bases: rely on water to produce OH<sup>-</sup> ions
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What is the significance of equilibrium in acid-base reactions?
Equilibrium determines the
concentration
of products and reactants
Strong acids
/bases favor products
Weak acids
/bases favor reactants
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What is the relationship between pH and acidity?
Lower pH: higher acidity
pH of 7:
neutral
Higher pH: lower acidity
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What is the role of water in acid-base chemistry?
Acts as both an acid and a base
Participates in
proton transfer
Exists in equilibrium with
H<sup>+</sup>
and
OH<sup>-</sup>
ions
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What are the units of K<sub>w</sub>?
Moles squared
per dm
to the minus six
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What does pH measure in a solution?
Concentration of
H+
ions
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Why is the pH scale logarithmic?
It converts small numbers into
manageable
values
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What is the pH of a neutral substance?
7
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What does a pH of 0 indicate?
Very
acidic
substance
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What is the equation to calculate pH?
pH = -
log<sub>10</sub>
[H<sup>+</sup>]
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How do you calculate the pH of hydrochloric acid with a concentration of 0.03 moles per cubic meter?
pH = -
log<sub>10</sub>
[0.03]
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What does a pH of 1.5 indicate about hydrochloric acid?
It is a
strong acid
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How can you calculate the concentration of H+ ions from pH?
Use the equation [H+] =
10<sup>-pH</sup>
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What is the concentration of H+ ions in nitric acid with a pH of 1.7?
[H+] =
10<sup>-1.7</sup>
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What is the value of K<sub>w</sub> at 298 Kelvin?
1 x 10<sup>-14</sup>
moles<sup>2</sup>
dm<sup>-6</sup>
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What is the relationship between strong acids and their dissociation?
Strong acids dissociate
fully
in solution
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How do you calculate the pH of a monoprotic acid like hydrochloric acid?
pH = -
log<sub>10</sub>
[concentration of acid]
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How does a diprotic acid differ from a monoprotic acid?
Diprotic acids produce two
H+
ions per
molecule
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What is the pH of 0.25 moles per cubic meter of hydrochloric acid?
pH =
1.6
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How do you calculate the concentration of H+ ions from a diprotic acid?
Concentration of H+
=
2
x concentration of acid
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How do you calculate the pH of sodium hydroxide?
Use the concentration of
OH-
ions
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What is the main difference in calculating pH for strong acids and strong bases?
Strong bases require
H+
concentration from
Kw
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How do you calculate the pH of a strong base like sodium hydroxide?
pH = -
log<sub>10</sub>
[H+
concentration
]
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What is the significance of the acid dissociation constant (K<sub>a</sub>)?
K<sub>a</sub> is used for
weak acids'
pH calculations
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Why do weak acids require the K<sub>a</sub> expression for pH calculations?
They dissociate only
slightly
in solution
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How do you calculate the pH of ethanoic acid?
Use
K<sub>a</sub>
and the concentration of acid
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What is the K<sub>a</sub> for ethanoic acid at 298 Kelvin?
1.76 x
10<sup>-5</sup>
moles per cubic meter
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How do you find the concentration of H+ ions from the pH of a weak acid?
Calculate H+ from pH using
10<sup>-pH</sup>
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What is the relationship between H+ concentration and pH?
Higher
H+ concentration means
lower
pH
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What is the significance of the square root in weak acid calculations?
It finds the
concentration
of
H+
ions
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