chem paper 2

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  • Rate of reaction is the speed at which a reaction happens
  • Rate is the change in a quantity divided by time
  • Quantity can be the mass or volume of reactant used or product formed
  • An experiment example is reacting hydrochloric acid and sodium thiosulfate
  • Another experiment is measuring the volume of gas produced using a gas syringe
  • Factors that increase the rate of reaction:
    • Increasing concentration of reactants in solution
    • Increasing pressure of gas reactants
    • Increasing surface area of solid reactants (crushing into a powder)
    • Increasing temperature, particles move more quickly and collide with more energy
  • Adding a catalyst increases the rate by reducing activation energy needed
  • Reversible reactions can go back to original reactants once products are made
  • Le Chatelier's principle states that a system at equilibrium will adjust to counteract changes
  • Increasing pressure favors the forward reaction, increasing concentration does the same for solutions
  • Increasing temperature favors endothermic reactions
  • Organic compounds have carbon forming the backbone of molecules
  • Crude oil consists mostly of hydrocarbons, mainly alkanes
  • Fractional distillation separates crude oil into different length alkanes
  • Longer alkanes have higher boiling points and are more viscous
  • Alkanes can be used as fuels and to make solvents, lubricants, detergents, and polymers
  • Polymers are made from alkenes, which have a carbon-carbon double bond
  • Alkenes can be tested with bromine water to check for unsaturation
  • Cracking breaks longer alkanes into shorter alkanes and alkenes
  • Alcohols end with -ol, can combust to produce carbon dioxide and water
  • Short alcohols can mix with water to form a solution
  • Oxidizing alcohols without combustion produces carboxylic acids
  • Polymers are long-chain molecules made from repeating monomers
  • Condensation polymerization joins monomers with two functional groups to form polymers
  • Amino acids are the building blocks of proteins, can be polymerized to make polypeptides
  • DNA is made from nucleotides and stores genetic code
  • Starch is a natural polymer made from repeating units
  • DNA is made from two polymers that spiral around each other in a double helix
  • DNA is made from four different monomers called nucleotides
  • Starch is a natural polymer with glucose as the monomer
  • Cellulose is a polymer made from beta glucose
  • Proteins have amino acids as their monomers
  • Melting point or boiling point can be used to determine if a substance is pure
  • Formulation is a mixture designed for specific purposes with specific quantities of substances
  • Chromatography is used to separate substances in a mixture
  • Chromatography involves a stationary phase (e.g., chromatography paper) and a mobile phase (e.g., water)
  • RF value is a ratio used in chromatography to identify substances in a mixture
  • Chemical tests for gases:
    • Hydrogen: burning splint produces a squeaky pop
    • Oxygen: relights a glowing splint
    • Carbon dioxide: turns lime water cloudy
    • Chlorine gas: bleaches damp blue litmus paper
  • Flame tests for metals:
    • Lithium: crimson flame
    • Sodium: yellow flame
    • Potassium: lilac flame
    • Calcium: orange-red flame
    • Copper: green flame
  • Carbonates react with acids to produce carbon dioxide gas