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GCSE
Chemical Changes
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Reactivity
: the tendency of a metal to form positive ions
Ore
: a type of rock that contains metal ions
Species
: a molecule or element within a chemical reaction/equation
metal + oxygen → metal
oxide
metal + water → metal
hydroxide
+
hydrogen
• Metals higher than carbon in the reactivity series are extracted using
electrolysis
– very
expensive
• Metals below carbon are extracted by
reduction
using
carbon
e.g. iron
oxide
is reduced in a
blast furnace
o This is because carbon can
displace
a metal from its
oxide
when a metal is less
reactive
than carbon
REDuction & OXidation occur at the same time – called
REDOX
•
strong acids
e.g. hydrochloric, nitric & sulfuric acids
o
completely ionised
in aqueous solution
▪ all
acid
particles disassociate to release
H+
ions
•
weak
acids e.g. ethanoic, citric & carbonic
acids
o only
partially ionised
in aqueous solution
▪ only a
small proportions
of acid particles disassociate to release
H+
ions
o ionisation of a weak acid is a
reversible reaction
▪ leads to an
equilibrium
of
undissociated
and
dissociated
acid
▪ since only a few acid particles release
H+
ions the position of equilibrium lies to the left
electrolytes
- liquids & solutions are able to conduct electricity (must be
ionic
compounds)
electrodes - solids that conduct
electricity
& are
submerged
in the
electrolyte
o Aluminium oxide is extracted from
bauxite
ore
o Aluminium oxide has a very
high
melting point, so adding cryolite
reduces
the melting point
▪
Cryolite
is an
aluminium
based compound with a
lower
melting point than aluminium oxide
• Positive
Al3
+ ions are attracted to the
negative electrode
(cathode)
o they gain
3
electrons to form aluminium atoms which sink to the
bottom
of the electrolysis tank
•
Negative
O2- ions are attracted to the
positive
electrode (anode)
o they
lose 2
electrons to form oxygen atoms which bond to form
O2
molecules which are
released
Aqueous solutions:
o At the
negative
electrode (cathode) –
H+
ions &
positive metal
ions are present
▪ If the metal is more
reactive
than
hydrogen
– hydrogen gas is produced
▪ If the metal is
less reactive
than hydrogen – the pure metal is produced (coats the cathode)
o At the
positive
electrode (anode) –
OHions
&
negative non-metal
ions are present
▪ If
halide
ions are present – the
halogen
gas is produced
▪ If halide ions aren’t present –
oxygen
gas is produced (
OH
ions discharged)
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