Chemistry: The study of matter, its composition, properties, and changes.
Matter: Anything that has mass and occupies space, essentially anything physically real.
Chemistry lies in the middle of the relationships between major branches of science, emphasizing its importance
Biochemistry is a field where biologists and chemists work together, showing overlap between biology and chemistry
Geochemistry is a field where geology and chemistry intersect, demonstrating overlap between these two disciplines
Chemistry is referred to as the "central science" as it links various fields of science together through their dependence on matter
KineticMolecularTheoryofMatter:
Describes the microscopic properties of atoms or molecules and their interactions
Leads to observable macroscopic properties like pressure, volume, and temperature
PhasesofMatter:
Matter can exist in different states: solid, liquid, and gas
Explained by the Kinetic Molecular Theory
Phase Changes:
Transitions matter can undergo from one phase to another
Elucidated by the Kinetic Molecular Theory
Kinetic molecular theory of matter: Matter is made up of particles that are constantly moving
Energy: All particles have energy, but the energy varies depending on the temperature the sample of matter is in
Temperature: The temperature of a substance is a measure of the average kinetic energy of the particles
Phase: A change in phase may occur when the energy of the particles is changed
Spaces: There are spaces between particles of matter
Intermolecular forces: There are attractive forces between atoms/molecules, and these become stronger as the particles move closer together. These attractive forces are called intermolecular forces
Gas shape and volume conform to the shapeofthecontainer
Gas properties include high compressibility and high ability to flow
Gas Properties: Compressibility (High), Ability to flow (High)
Liquid conforms to the shapeofthecontainer; volume limitedby surface
Liquid has compressibility (Verylow) and the ability to flow (Moderate)
Solid: Maintains its ownshape and volume
Properties: Compressibility (Almostnone)
Melting (or fusion) is the process of a solid turning into a liquid
Vaporization is the transformation of a liquid into a gas, which can occur through boiling or evaporation
Condensation is the change of a gas into a liquid
Freezing (or solidification) is the transition of a liquid into a solid state
Deposition is the conversion of a gas directly into a solid without passing through the liquid phase
Sublimation is the process of a solid turning directly into a gas without becoming a liquid first
Molecules: Units that interact to form an assembly.
IntermolecularForces: Forces that are interrelated by assembly.
VanderWaalsForces:
Intermolecular forces including LDF, attraction, and repulsions between atoms, molecules, and surfaces
Dipole-dipoleinteractions:
Attraction between partial charges in different molecules, aligning positive and negative ends
London dispersion force:
Temporary attractive force due to temporary dipoles in adjacent atoms, also known as induced dipole-induced dipole attraction
Polar vs. Nonpolar Molecules:
Polarmolecules have an electronegativity difference
Nonpolarmolecules share electrons equally or cancel polar bonds
HydrogenBonding:
Attractive force between hydrogen and electronegative atoms like oxygen, nitrogen, or fluorine in different molecules
Ionicinteractions are between charged atoms or molecules called ions
Positively charged ions are cations, such as Na(+), Li(+), and Ca(2+)
Negatively charged ions are anions, such as Cl(-), Br(-), and HO(-)
Coulomb's Law describes the attractive forces between oppositely charged ions
The force increases with charge and decreases as the distance between ions increases