Alkanes has a tetrahedral structure with the bond anle 109.5
Effect of Carbon chains on boiling point of alkanes
Boiling point increases as carbon chains increase in number, due to this surface area increases and there are more points of surfacecontact leading to more London forces
Effect of branching on boiling point of alkanes
Boiling point decreases as branching increases due to fewer point of surfacecontact which reduces london forces
Heterolytic fission
Bothelectrons in the covalent bond move onto one atom resulting in positively and negatively charged ions
Homolytic fission
One electron from the covalent bond moves onto each atom to form two free radicals
Remebering Hetero and homo-lytic fission
Hetero is straight and you only like one (both electrons move onto one atom)
Free radical
A highly reactive species containing an unpaired electron