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AS Chemistry
Module 4
Alkenes
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Are alkenes saturated or unsaturated ?
unsaturated
What is the general formula for alkenes ?
CnH2n
What does a C=C bond consist of ?
a
sigma
bond and a
pi
bond
How is a pi bond formed ?
The
sideways overlap
of p orbitals formed
above
and
below
the
plane
of the
carbon
atoms.
What does a pi bond prevent ?
bond
rotation
What shape and bond angle does each C in the C=C bond have ?
Shape=
triganol planar
Bond Angle =
120
Definition of stereoisomerism.
Compounds with the same
structural formula
but a
different arrangement
of
atoms
in space.
What are the two types of stereoisomerism ?
E
/
Z
and
optical
What is the criteria of E/Z isomerism ?
C=C
and each
carbon
on the
double
bond must be attached to
two different
atoms.
What is the difference between E isomerism and Z isomerism ?
In E isomerism the
high
priority groups are on
opposite
sides but for Z isomerism they are on the
same
side.
What is the criteria for cis trans isomers ?
Two
different groups on each
C
on
C=C bond
and two of these
substituent
groups are
hydrogen.
What is the difference between cis and trans isomerism ?
In cis isomerism the hydrogens are on the
same side
of the C=C and in trans isomerism the hydrogens are
diagonally opposite.