Vital tray-based bleaching evolved from observed tooth lightening when carbamide peroxide was used in a splint after periodontal treatment. The active ingredients of these systems is carbamide peroxide gel. The exact mode of action is unclear, but again thought to be an oxidising process. 10% Carbamide peroxide breaks down into approx 3% H2O2, and urea. These then break down to oxygen, water, ammonia and carbon dioxide. Urea and H2O2 have small molecular weight and can therefore diffuse rapidly through enamel and dentine. This may explain the transient pulpal sensitivity sometimes experienced.