Polysaccharides are polymers made up of many monosaccharide subunits linked by condensation reaction, examples include starch, glycogen, cellulose, and chitin
Starch has two variants: amylose, made up of unbranched chains of glucose, and amylopectin, made up of highly branched chains due to 1,4 and 1,6 glycosidic bonds
Cellulose cannot be digested by humans due to the 1,4-glycosidic bonds, but can be broken down by organisms possessing cellulase enzymes to release glucose