Stable nuclei lie along the central orange belt that curves upwards:
light stable nuclei have approximately the same number of protons and neutrons
heavy stable nuclei have more neutrons than protons to help bind the neutron together.
Emitters:
alpha emitters tend to be large nuclei because the strong nuclear force is unable to overcome the electrostatic force of repulsion between protons.
beta minus emitters occur to left of the stability belt where isotopes are neutron -rich
beta plus emitters occur to right of the stability belt where isotopes are proton -rich
A radioactive decay series , when a radioactive isotope decays into an isotope which itself is unstable , can be represented on the N-Z graph.
the emission of alpha or beta radiation can leave a nucleus in an excited state. the nucleus loses energy and returns to its ground state by emitting gamma radiation.
the energy changes in a nucleus can be shown using a nuclear energy level diagram.
Metastable states:
Excited states that last for a significant period are called metastable states.
Metastable:
Isotopes in a metastable state can be useful in medicine because they can be separated and used as a source that emits only gamma radiation.
Estimating the nuclear radius:
The maximum size of a nuclear radius can be estimated from the distance of closest approach of an alpha particle.
Estimating the nuclear radius:
At the distance of closest approach to a nucleus of charge Q, the electric potential energy of the alpha particle will be equal to its kinetic energy:
Ek = 1/4 pie e0 x Q Q / r
r = Q Q / 4 pie e0 x Ek
Measuring nuclear radius:
Electron diffraction can be used to determine the radius of nuclei more accurately.
Measuring nuclear radius:
High energy electrons have a de Broglie wavelength small enough that they are diffracted by the nuclei of atoms. Graphs can show how the intensity varies with the angle for electron diffraction by a nucleus.
Measuring nuclear radius:
the angle of first minimum is given by sin0 = 1.22 x de broglie wavelength / d
where d is the diameter of the nucleus
Data from electron diffraction experiments show that the radius of a nucleus R is related to its nucleon number A by:
R = R0 x A^1/3
The equation R = R0 x A^1/3 can be used to show that all nuclear material has the same density:
assuming nucleus is spherical its volume is,
V = 4/3 pie R^3 = 4/3 pie (R0 x A^1/3)^3 = 4/3 pie r^3 A
substituting the equation for density:
p = m / 4/3 pie r^3 A
p = Au / 4/3 pie r^3 A = p = u / 4/3 pie r^3 = p = 3u /4 pie r^3 A
p = 3.4x10^17
The mass m of any object increases or decreases when it gains or loses energy E:
E = mc^2
this applies to all energy changes
Atomic and nuclear masses are often expressed in atomic mass units where :
1 u = 1/12 mass of a carbon 12 atom
1 u = 1.661x10^-27
1 u = 931.5 Mev
The mass defect:
in any change where energy is released the total mass after the change is always less than the total mass before the change because some energy is converted to released energy.
The mass defect:
The mass of a nucleus is less than the total mass of the individual nucleons of which it is formed.
The mass defect:
the mass defect of a nucleus is the difference between the mass of a separated nucleons and the mass of the nucleus. This is equal to the energy released when a nucleus forms from separate protons and neutrons.
Nuclear fission is the process by which a large unstable nucleus splits into two smaller nuclei.
Nuclear fusion is the process by which small nuclei join to form a larger nucleus.
energy is released when nuclear fission and fusion take place because the resulting nuclei have higher binding energy per nucleon.
Induced nuclear fission is the splitting of heavy nuclei by firing slow-moving thermal neutrons at them.
Thermal neutrons are those made in thermal equilibrium with the surroundings.
A chain reaction can occur when the neutrons released by the fission of a nucleus go on to induce fission in other nuclei.
Critical mass is the minimum mass a fissile material (able to undergo fission) must have fir a self-sustaining chain reaction to occur.
The binding energy of a nucleus is the work that would need to be done to separate it into its constituent nucleons , and is equal to the mass defect:
binding energy of nucleus = mass defect x c^2 = mc^2
The binding energy per nucleon is measure of the stability of a nucleus - the greater the binding energy the more stable the nucleus is.
The change in binding energy per nucleon is equal to the energy released from fission or fusion.
Iron -56 has the highest binding energy per nucleon, so is the most stable nucleus.
binding energy per nucleon is increased and so energy is released by fusion of small nuclei.
binding energy per nucleon is increased and so energy is released by fission of large nuclei.
Induced nuclear fission is used to create a controlled chain reaction in nuclear reactors in power stations.
Control rods:
absorb neutrons produced in fission and are raised from and lowered into the reactor to control the rate of fission.
Coolant:
needs high specific heat capacity to absorb lots of the energy released in fission, and to be easily pumped round the reactor to be replaced.
moderator:
has similar mass and kinetic energy to fast moving neutrons released in fission, slow the neutrons so they become thermal neutrons , and have a higher probability of being absorbed.
Safety features of reactors:
the reactor is surrounded by thick concrete walls to absorb the radiation emitted.
fuel rods are radioactive so they are inserted and removed from the reactor by a remote devices.
in emergencies control rods are automatically inserted into the core to bring fission to a stop.
Disposal of fuel rods:
spent rods are hot and radioactive , they are unstable and emit radiation.
remote handling rods are used to remove fuel rods and placed in cooling ponds
after cooling fuel rods are reprocessed so they can be used in practical applications.
Advantages and disadvantages of nuclear power:
nuclear power can generate large amounts of electricity to meet high power needs
dont produce greenhouse gasses
large amounts of nuclear waste are produces and probability of reactor accidents.
The rutherford scattering experiment:
a beam of alpha particles were directed at a thin gold foil.
Occurs in a vacuum so that no collisions between air particles and alpha particles can occur.
The experiment was done in order to determine structure of an atom.
Due to the nucleus repelling alpha particles and causing deflection it was deduced that the nucleus had a positive charge.