Development that meets the needs of current generations without compromising the ability of future generations to meet their own needs
Producing potable (safe to drink) water in the UK
1. Choosing an appropriate source of fresh water
2. Passing the water through filter beds to remove any solids
3. Sterilising to kill microbes
Sterilising agents for potable water
Chlorine, ozone or ultraviolet light
Chlorine
Toxic gas so the amount added to water has to be carefully monitored
Ultraviolet light
Kills microbes without adding chemicals but is more expensive
Desalination
1. Distillation or processes that use membranes such as reverse osmosis
2. Requires large amounts of energy
Reverse osmosis
Sea water is passed through a membrane that only allows through the water molecules
Needs high pressure to push the water through the membrane
The high pressure requires a lot of energy to produce
Wastewater treatment
1. Removal of organic matter and harmful microbes/chemicals
2. Sewage and agricultural waste water
3. Industrial waste water
Sewage treatment
1. Screening and grit removal
2. Sedimentation to produce sewage sludge and effluent
3. Anaerobic digestion of sewage sludge
4. Aerobic biological treatment of effluent
New mining methods avoid the disadvantages of traditional mining methods of digging, moving and disposing of large amounts of rock
Phytomining
Uses plants to absorb metal compounds from the soil
The plants are harvested and then burned to produce ash that contains the metal compounds
Bioleaching
Uses bacteria to produce leachate solutions that contain metal compounds
Phytomining and bioleaching
Need less energy than traditional methods
Can work on low concentration ores
But are slow to carry out
Life Cycle Assessments (LCAs)
1. Extracting and processing raw materials
2. Manufacturing and packaging
3. Use and operation during its lifetime
4. Disposal at the end of its useful life, including transport and distribution at each stage
Reducing resource use
Reduction in use, reuse and recycling of materials by end users reduces the use of limited resources, energy consumption, waste and environmental impacts
Advantages of recycling
Less acid rain (pollution)
Metal ore reserves last longer / conserved
Energy for extraction saved
Less mining / quarrying
Less waste
Less landfill
Creates local employment
Disadvantages of recycling
Collection problems
Transport problems/ cost of transport
Difficult to separate metal from appliances/sort
Corrosion
Destruction of materials by chemical reactions with substances in the environment, e.g. rusting
Preventing corrosion
1. Applying a coating that acts as a barrier, such as greasing, painting or electroplating
2. These methods stop the air or water coming into contact with the metal
Sacrificial protection
More reactive metal will corrode instead of the less reactive one, e.g. zinc is used to galvanise iron and when scratched, provides sacrificial protection because zinc is more reactive than iron
Alloys
Bronze - copper and tin, used for making statues and decorative objects
Brass - copper and zinc, used for producing water taps
Electroplating
Methods that stop the air or water coming into contact with the metal
Sacrificial protection
1. Some coatings are reactive and may contain corrosion inhibitors or a more reactive metal
2. If two metals are in contact the more reactive metal will corrode instead of the less reactive one, e.g. zinc is used to galvanise iron and when scratched, provides sacrificial protection because zinc is more reactive than iron
Alloys
Bronze - an alloy of copper and tin, used for making statues and decorative objects
Brass - an alloy of copper and zinc used for producing water taps and door fittings
Gold used as jewellery is usually an alloy with silver, copper and zinc (The proportion of gold in the alloy is measured in carats, with pure gold being 24 carat, e.g. 18 carat gold is 75% gold)
Aluminium-magnesium alloys are low density and used in aerospace manufacturing
Steels - alloys of iron that contain specific amounts of carbon and other metals. High carbon steel is strong but brittle. Low carbon steel is softer and more easily shaped. Steels containing chromium and nickel (stainless steels) are hard and resistant to corrosion
Polymer properties
Depend on what monomers they are made from and the conditions under which they are made
Low density (LD) and high density (HD) poly(ethene)
Produced from ethene, using different catalysts and reaction conditions
Thermosetting polymers
Do not melt on heating
The polymer molecules are linked to each other by strong cross-links
Thermosoftening polymers
Soften easily on heating and can then be remoulded, keeping the new shape on cooling
The polymer molecules are attracted to each other by weak intermolecular forces
Glass making
1. Most of the glass we use is soda-lime glass, made by heating a mixture of sand, sodium carbonate and limestone
2. Borosilicate glass, made from sand and boron trioxide, melts at higher temperatures than soda-lime glass
Clay ceramics making
Clay ceramics, including pottery and bricks, are made by shaping wet clay and then heating in a furnace
Composite formation
1. Fibres or fragments of one material (reinforcement) are surrounded by a binder/matrix material that holds these fibres/fragments together
2. E.g. fibreglass - glass fibres bound together in a polymer, used for making storage tanks
Haber process
1. The purified H2 and N2 gases are passed over Fe catalyst at a high temperature (about 450 °C) and a high pressure (about 200 atm)
2. Fe speeds up the rate of reaction, so that a lower temperature could be used in the process
3. Some of the hydrogen and nitrogen reacts to form ammonia. N2 + 3 H2 ⇌ 2 NH3
4. The reaction is reversible so ammonia breaks down again into nitrogen and hydrogen
5. On cooling, the ammonia liquefies and is removed. The remaining hydrogen and nitrogen are recycled. This means almost no material is wasted
6. Ammonia is used for production of nitrogen-containing fertilisers
The Haber process uses high T and p conditions
The conditions are a compromise between rate and the yield
The reaction is exothermic. An optimum temperature of 450 °C is used. Using a lower temperature would give a higher yield, but the rate of NH3 production would be too slow
A pressure of 200 atm is used. Using a higher pressure would give a higher yield, but would be too expensive, because of the cost of energy to produce the high pressure
Compounds of nitrogen, phosphorus and potassium
Used as fertilisers to improve agricultural productivity
NPK fertilisers contain compounds of all three elements
Industrial production of NPK fertilisers
1. Ammonia can be used to manufacture ammonium salts. The ammonium sulfate, phosphate, and nitrate can be produced by reaction of ammonia with the requisite acid
2. 2 NH3 + H2SO4 → (NH4)2SO4
3. 2 NH3 + H3PO4 → (NH4)3PO4
4. NH3 + HNO3 → NH4NO3
5. Nitric acid is itself made from ammonia
Utilisation of phosphate rock in fertiliser production
1. Phosphate rock is reacted with nitric acid to produce phosphoric acid and calcium nitrate
2. Phosphate rock can be reacted with sulfuric acid to produce a mixture of calcium phosphate and calcium sulfate
3. Phosphate rock can be reacted with phosphoric acid to produce calcium phosphate