Cards (7)

  • Reversible Reaction - the products can react with each other to produce the original reactants
  • Dynamic Equilibrium - the forward/backward reactions are happening at the same time/rate and concentrations of reactants/products have reached an unchangeable balance
    This can only happen if a reversible reaction happens in a closed system
  • The Haber Process - nitrogen and hydrogen react to form ammonia:
    • nitrogen from the air (78%)
    • hydrogen from natural hydrocarbons (natural gas and crude oil)
    • conditions include: 450 'C, 200 atmospheres pressure and an iron catalyst
  • Le Chatelier's Principle - if there is a change in concentration, pressure or temperature then the equilibrium position will move to counteract the change
  • Temperature - exothermic in one direction (ammonia) and endothermic in the other (reactants)
    • decreasing temperature will make the equilibrium favour the exothermic direction to produce heat (ideal for Haber Process)
    • increasing temperature will make the equilibrium favour the endothermic direction to absorb heat
  • Pressure - only effects equilibria involving gases (ammonia gas)
    • increasing pressure will make the equilibrium favour the side with fewer moles to reduce pressure (ideal for Haber Process)
    • decreasing pressure will make the equilibrium favour the side with more moles to increase pressure
  • Concentration
    • increasing reactant concentration will create more product to use up reactants (ideal for Haber Process)
    • increasing product concentration will create more reactants
    • decreasing concentration has the opposite effect