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Module 4
#4.1 basic concepts and hydrocarbons
properties of alkanes
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alkanes bonds are non polar because carbon and hydrogen have similar electronegativity
shape and angle of an alkane is
tetrahedral 109.5
degrees
sigma bond is a covalent bond which has a direct
overlap
of
electron clouds
of the bonding atoms
alkanes have
London
forces ->
induced dipole-dipole
interaction, because bonds are non-polar
boiling point increasees as
alkane chain length increases
because more surface area + so more number of
induced dipole-dipole
interaction
-> therefore more energy required to
overcome
the
attraction
branched molecules have lower boiling points because they have
fewer
surface area + hence less
induced dipole-dipole
interactions
alkanes are insoluble in water because
hydrogen
bonds in water are stronger than alkanes'
London
forces of attraction
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