Intramolecular forces are forces between atoms within a molecule.
types of intramolecular force: ionic, metallic, covalent
Ionic bonding is the electrostatic attraction between oppositely charged ions. Formed by the transfer of electrons (metal and nonmetal). Has formal charge (+,-)
Metallic bonding is the electrostatic attraction between delocalized electrons and the positive metal ions. Formed by sharing electrons of two or more metals. Has partial charge (Cation (+) with delocalized/free electron (-)).
delocalized electrons are electrons in a molecule, ion or solid metal that are not associated with a single atom or a covalent bond.
Nonpolar Covalent Bonding is when there is equal distribution of electrons because both atoms have similar electronegativities. There is no polarity present.
Covalent bonding is the sharing of electrons between two or more nonmetals in a chemical reaction.
types of polarity in covalent: polar and non-polar
polar: unequal sharing of electronegativity eg H20
non-polar: equal sharing of electronegativity eg. O2, Cl2
intermolecular forces are forces between molecules
fill in the blanks in the table below
A) ionic
B) ionic
C) polar covalent
D) polar covalent
E) hydrogen bond
F) non-polar covalent
G) polar covalent
H) non-polar covalent
Surface Tension is the force that causes the surface of a liquid to contract. Water, in particular, has high surface tension because of hydrogen bonds. Temperature affects surface tension
Viscosity is the ability of the liquid to flow and/or the liquid’s resistance to flow between the molecules of a liquid when they pass each other.
High resistance, high viscosity
High temperature, low viscosity
Vaporization is the change of state from liquid to gas while the opposite is condensation.
Includes evaporation and boiling
Gas and vapor are similar but not the same
Volatile liquids tend to evaporate faster than water.
Boiling point of water is 100 degree C
Molar heat of vaporization is the formation of liquid to gas with the addition of heat as a form of energy.
Heat of vaporization is the amount of heat needed to vaporize a given amount of liquid at its boiling point
the unit of crystalline solids is called unit cell
the structure of solids can be subdivided into simple and closed-packed.
In close-packed structure, the gap between the particles is called the void.
Amorphous Solids’ atom arrangement is not organized as definite pattern.
Pseudo-solids/supercooled liquids
Ranged melting point
Isotropic – same response in any directions/same physical properties in different directions.
Crystalline Solids’ atom arrangement is definite and organized.
True solids
Sharp melting point
Anisotropic – different response in any directions/different physical properties in different directions.