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Acid-Base Equilibrium
Acids and Bases
Bronstead-Lowry Theory
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Arrhenius (or
hydrolisis
) has some shortcomings, therfore a more comprehensive theory is needed (
BLT
)
Bronstead-Lowry Theory (BLT):
Acid
- an entity that donates a proton, H+
Base
- an entity that accepts a proton, H+
every BLT reaction has
2
conjugate acid-base pairs
ex.
CH3COOH
and
CH3COO-
Conjugate
acids and bases differ by one
H+
abd are next to each other in the data booklet
only transfer one
proton
(H+) at a time in
BLT
reactions
Amphiprotic
- entities that can both accept and donate a proton. Whether it is an
acid
or a base depends on what it is paired with
favours products (>
50
%)
SA down to
B-
WA down to
B-
favors
reactants (<
50
%)
WA up to
B-