Electrophilic Addition

Cards (5)

  • Electrophilic Addition reactions with alkenes always proceed through a carbocation intermediate (ions with a positive charge on carbo).
  • Reaction with Halogens
    e.g Br2
    The Electron deficient Br2 forms a temporary dipole as it approaches the electron rich C to C double bond(repels the far b)
  • Alkenes are highly reactive, as the P electrons form a double bond meaning a high electron density above and below the double bond forming and electron rich double bond
  • Reaction with Hydrogen Halides:
    e.g HBr
    Bromine is more electronegative than hydrogen and therefore H acts as the electrophile and is attracted to the Carbon double bonds high electron density
  • Reaction with Sulphuric acid:
    Alkenes react with Sulphuric acid to form alkyl hydrogen sulphates, and adding water causes hydrolysis forming an alcohol