Hydrogens attached to the carbon atoms are on the opposite side of the carbonchain
Sources of trans fatty acids
Not found naturally in high quantities in any food, artificially produced trans fats used in commercially produced foods such as biscuits, cakes, pastries, hydrogenated vegetable fats for deep frying, Copha
Cholesterol- Sterols
Most common is cholesterol and is also comprised of carbon, hydrogen and oxygen
Cholesterol features glycerol and fattyacidchains similar to triglycerides.
However, in cholesterol, fattyacidchains are fused as rings, giving it a steroid section and is classification of a sterol.
Excess can lead to some health concerns in relation to atherosclerosis and heartdisease
Sources of cholesterol
Most cholesterol is made in the liver, small amount comes from the diet (meat, fish, eggs, dairy)
Types of lipoproteins
Chylomicrons
Very-low density lipoprotein (VLDL)
Low-density lipoprotein (LDL)
High-density lipoprotein (HDL)
Dependent on size and density
Lipoproteins
Cholesterol is a waxy substanceand only slightlysoluble in water and blood (hydrophobic), therefore it requires transport with hydrophilic (mix and dissolve in water) proteins in molecules called lipoproteins
Consists of hydrophobiccore (cholesterol & triglycerides)
Core is surrounded by hydrophilic membrane consisting of phospholipids, freecholesterol and protein
LDL cholesterol
Smaller than VLDL
Derived from VLDL
Greatercholesterol and fewertriglycerides than a VLDL
LDLcirculates throughout the body delivering cholesterol - lead to depositingLDL on arterywalls and becoming trapped (forming plaque)
HDL cholesterol
Smallest
Produced by the Liver
HDL removesexcesscholesterol from the cells and carries it back to the liver for recycling and disposal
Lowest proportion of lipids and highest proportion of protein
30% of our daily energy should come from fats and oils, no more than 10% from saturated fat and no more than 1% from trans fats
Source of Energy
Provide 37.7kJ per 1g, energy storage (adiposetissueunder skin and aroundorgans)
When energy is required, triglycerides are brokendown into glycerol and fattyacidchains from fat cells in adiposetissue and used to createenergy in the form of ATP
30% of our daily energy should come from fats and oils
No more than 10% from saturatedfats
No more than 1% from transfat
Fat keeps the feeling of satiety and regulateappetite
Functions of essential fatty acids (omega-3 and omega-6)
The body cannotsynthesise these and therefore they must be consumed from the diet
Overall support functioning of the circulatory and immunesystems
Omega 3: keeps the heartbeatingregularlyreducing the risk of abnormal heartbeat (arrhythmia) thinning the blood and therefore reducing the risk of clotting and supporting the immunesystem
Omega 6: also assists in bloodclottingprocesses
*both essential fatty acids are useful in fetal/ infantbrain development and in the reduction of low-densitylipoproteins
Functions of Cholesterol
Cholesterol is needed by cells for its structuralrole in the cellmembrane as it createsstability
Cholesterol is also required for the synthesis of bodycompounds including bile, hormones and VitaminD
Cholesterol is a waxysubstance that requires a transportmolecule to move around the bloodstream (same as triglycerides)
Limit saturated fats, choose lean meats, remove skin & fat from meats, choose low-fat/reduced dairy, choose unsaturated fats where possible (nuts, veg oils, fish, avocado), choose cooking methods that use less addition of fats
Lipids
The lipid family includes triglycerides (fats & oils) and phospholipids and sterols
95% of the foods we eat include triglycerides
5% of lipids are phospholipids and sterols
Triglycerides are composed of carbon, hydrogen, and oxygen and supply the body with energy
Come in two main forms
Fats that are solid at room temperature - higher melting points
Oils that are liquid at room temperature - lower melting point
a food is classified by the type of fat that is more predominant in the foodsource
Structure and Classification of Lipids
All fatty acids have the same basic structure - a chain of carbon and hydrogenatoms with an acid group (COOH) at one end and methylgroup (CH3) at the other end.
They differ from one another by the length of carbonchains and in the number and location of their doublebonds.
Most naturally occurring have an even number of carbon chains (4-24)
12-24 for meatfishvegetableoils
10dairy products
Unsaturated Fatty Acids
Monounsaturated Fatty Acids
Polyunsaturated Fatty Acids
Bonds
oxygen can only form two bonds, hydrogen can only form one bond, and carbon can only bond four bonds
Naturally Occurring Unsaturated Fatty Acids
have double bonds known as cis, meaning the hydrogen atoms are attached to the carbon atoms with a double bond on the same side as the carbon chain
Hydrogenation
Trans-fatty acids are mainly made through a process called hydrogenation – trans fats are known as hydrogenated fats
Hydrogenation is a process by which vegetable oils are converted to solid fats simply by adding hydrogen atoms.
During hydrogenation, the double bonds break and a hydrogen atom is added, creating a trans-fatty acid – becomes saturated
This process converts unsaturated fatty acids to saturated acids
Trans-fats form when manufacturers turn liquid oils into solid fats.
Why Manufactures Prefer Trans Fatty Acids
Longer shelf life
Improves texture - makes them more solid
Reduce Rancidity - change in colour, smell, and taste
Sources of Trans Fatty Acids
Not found naturally in high quantities in any food
Artificially produced transfats used in commercially produced foods such as biscuits, cakes, pastries
Hydrogenated vegetablefats for deep frying
Copha
Process of Fatty Acids
Fatty acidsrarely occur free in food or in the body and are most often attached to a glycerol molecule via their acid end, making a triglyceride.
To make a triglyceride, a series of condensation reactions combine a hydrogen atom from the glycerol and a hydroxyl group (OH) from a fattyacid, forming a molecule of water. A triglyceride may be composed of a mixture of more than one type of fattyacid
Chylomicron
Largest
Least dense
They transport lipids (triglycerides and cholesterol) to cells all over the body and become smaller as their contents gets depleted
Very Low Density Lipoproteins
Smaller than chylomicrons
Produced by the liver and are triglyceride rich
Transport triglycerides from the liver to body cells (muscle, adipose tissue) - as they deplete in triglycerides, they shrink in size shifting to an LDL
Transportation of Storage and Fat Soluble Vitamins
Fatsoluble vitamins: A, D, E, K
These congregate with triglycerides during digestion and move into the bloodstream and travel to adipose tissue where they are stored until needed.
Therefore, triglycerides are also considered to provide storage for fat-soluble vitamins.
*lipoproteins are required to transport fat soluble molecules as they are hydrophobic
Cushioning and Insulation of Vital Organs
Triglycerides are stored in fat cells found aroundinternal organs (visceral fat) and under the skin.
This adiposetissue provides protective cushioning and thermoregulation, specifically insulation as adipose tissue generates heat.
Lipids
Important in the diet as they are an energy source, protect organs, carry/store fat-soluble vitamins, synthesis of Vit D, bile & hormones, cell membrane structure
30% of our daily energy should come from fats and oils