Representing the formulae of organic compounds

Cards (12)

  • The molecular formula shows the number and typeof atoms of each element in a molecule. It does not show how the atoms are joined together and different molecules can have the same molecular formula
  • The empirical formula is the simplest whole-number ratio of the atoms of each element present in a compound.
  • The general formula is the simplest algebraic formula for any member of a homologous series. It can be used to generate the molecular formula of any member of that homologous series.
  • General formula of alkanes = CnH2n+C_nH_2n+22
  • General formula of alkenes = CnH2nC_nH_2n
  • General formula of alcohols = CnH2n+C_nH_2n+1OH1OH
  • General formula of carboxylic acids = CnH2nO2C_nH_2nO_2
  • General formula of ketones = CnH2nOC_nH_2nO
  • A displayed formula shows the relative positioning of all the atoms in a molecule and the bonds between them
  • The structural formula uses the smallest amount of detail necessary to show the arrangement of the atoms in a molecule. It shows clearly which groups are bonded together. E.g. structural formula of butane: CH3CH2CH2CH3CH_3CH_2CH_2CH_3 or CH3(CH2)2CH3CH_3(CH_2)_2CH_3
  • A skeletal formula is a simplified organic formula. You remove:
    All carbon and hydrogen labels from carbon chains
    Any bonds to hydrogen atoms
    This leaves just a carbon skeleton and any functional groups. In skeletle formulae:
    A line represents a single bond
    An intersection of two lines represents a carbon atom
    The end of a line represents a (-CH_3) group.
  • When functional groups are present in a molecule, they must be included in the skeletal formula