Materials where electrons can't flowback, so the transferred electrons leave a positive static charge on the material that lost them and a negative static charge on the material that gained them
Only the negative electrons are transferred, the positive static charges occur because an object has lost negative charge, not because it's gained positive protons
Charges can sometimes build up on conductors too, like on the metal frame of a car, which can then discharge through a person touching the car, causing a small spark