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Physical Chemistry
Amount of substance
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Cards (92)
Relative Atomic Mass
The
average
mass of an atom of an
element
, compared to that of the mass of
1/12th
of the average mass of an atom of
carbon-12
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Relative Molecular Mass
The
average mass
of one molecule compared to
1/12th
of the mass of one atom of
carbon-12
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Avogadro Constant
The number of particles in one mole of an atom:
6.022
x 10^
23
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Solvent
A liquid that can have a
substance
dissolved into it
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Solute
A
solid
that can be
dissolved
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Solution
A
solute
dissolved in a
solvent
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Ideal Gas Equation
pV
=
nRT
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Concentration
Moles
/
Volume
Amount of substance in moles dissolved in 1dm3 of solution
Mol dm-3
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Moles (mass)
Mass
/
Mr
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Atom Economy
Mr
of
producta
/ sum of
Mr
of all
reactants
x
100
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Percentage Yield
(
actual output
/
predicted output
) x
100
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Calculating empirical formula
1. % by
mass
2. Divided by
Ar
3. Divide by
smallest
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Calculate molecular formula
Relative molecular mass
divided by
relative mass
of
empirical formula
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equation for amount of moles (Avogadro constant)
amount of moles
=
number of particles
/
Avogadro constant
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4 reasons for lack of 100% percentage yield?
loss by
mechanical
transfer, loss during
separating
technique, unwanted
side reactions
, reaction not
complete
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units
1cm3
-
1ml
1dm3
-
1l
1dm3
-
1000cm3
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what is titration an example of?
volumetric analysis
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2 reasons why conical flasks are used in titration?
1. can
swirl
reactant easily
2.
sloped
sides ensure solution can not
spill
out
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what is the dilution factor? how is it calculated?
the amount the
original
solution is
diluted
by.
new total volume
/ volume of
original
solution added
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what is the dilution factor of 25cm3 to 250cm3
10
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what is important about the first titre?
it should be
rough
and
bigger
than the two
accurate
titrations
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what is a standard solution?
a
solution
of known
concentration
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what should values be recorded to in a titration?
0.05cm3
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what should two accurate titre values be?
within
0.10cm3
of each other
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how to convert from gdm-3 to moldm-3?
gdm-3 multiplied by Mr
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equation for percentage error?
error of
equipment
/
volume
of solution
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what kind of titration is phenolphthalein used for?
a strong and weak
acid-strong base
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what is the colour of phenolphthalein in 3 solutions?
acid
-
colourless
neutral
-
colourless
alkaline
-
pink
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what is the colour of methyl orange in 3 solutions?
acid
-
red
neutral
-
orange
alkaline
-
yellow
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which solution goes in the conical flask?
alkali
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which solution goes in the burette?
acid
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what is the molar volume?
1
mole of a gas occupies a volume of
24dm3
at room temperature and pressure
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equation for moles (gas)
moles
=
volume
/
24dm3
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what three factors does the ideal gas equation relate?
1. as pressure
increases
, the volume of a gas
decreases
2. as temperature
increases
, the volume of a gas
increases
3. the amount of gas in moles is directly
proportional
to its volume
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Ideal Gas Eqaution
pV
=
nRT
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How do you convert Celsius to Kelvin?
K =
C
+
273
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what is volume measured in ideal gas equation?
m3
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how to convert from m3, dm3, cm3
1m3 =
1000dm3
=
1000000cm3
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what does percentage yield not take into account?
any waste products
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the mole of a substance
is the
amount
of that
substance
that contains as many
particles
(atoms or molecules or ions) as there are atoms of C¹² in
12g
of C¹². (or
Avogadro's
constant)
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