The first ionisation energy is the amount of energy required to remove one mole of electrons from one mole of gaseous atoms
Factors affecting ionisation energy
shielding
nuclear charge
distance from nucleus
as you move across a period, the general trend is for ionisation energies to increase as the nuclear charge increases and the atomic radium decreases however there are small drops between groups 2 and 3 and groups 5 and 6
the drop in ionisation energy between group 2 and 3 across period 3 is due to aluminium's outer electron being in the 3p orbital so has a higher energy level and more shielding than the 3s orbital
the drop in ionisation energy between group 5 and 6 across period 3 is because the outer electron is being removed from an orbital containing two electrons and the pair of electron repulse each other