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Cards (7)
stereoisomerism:
same molecular formula but different spatial arrangement of atoms
stereoisomerism happens with
unsymmetrical carbons
with
chiral centres
enantimor:
2 possible isomers (mirror images) that form because of chiral centres
each enantimor causes the
rotation of plane polarised light by 90 degrees in the opposite direction
racemic mixture:
contains equal amounts of enantimors
racemic mixtures are
optically inactive
->
opposite directions of rotation
by each enantimor
cancels out
optical isomers can form because of
nucleophilic addition
reactions - nucleophile attacks a
carbonyl
group from
above or below c=o bond