Sodium ions are actively transported out of the cells into the blood by the sodium-potassium pump which creates a concentration gradient.
This causes sodium ions to diffuse into the cell (They do this via the sodium-glucose co-transporter proteins)
The co-transporter carries glucose into the cell with sodium and so thus the concentration of glucose inside the cell increases.
Glucose diffuses out of the cell, into the blood (down the concentration gradient) through a protein channel by facilitated diffusion.