How do you carry out fractional distillation?
1) Pour your mixture of liquids into a flask. Then attach a fractionating column and condenser above the flask.
2) Gradually heat the flask. The different liquids will all have different boiling points so they will evaporate at different temperatures.
3) The liquid with the lowest boiling point evaporates first. and when the temperature on the thermometer reaches the boiling point of this liquid, it will reach the top of the fractionating column.
4) Liquids with higher boiling points might also start to evaporate but the column is cooler towards the top, so they will only get part of the way up before condensing and running back down towards the flask.
5) When the first liquid has been collected, raise the temperature until the next one reaches the top and is ready to be evaporated.