Isotopes are atoms of the same element with the same number of protons but a different number of neutrons. They have the same atomic number but different mass numbers.
Atoms are made up of 3 subatomic particles:
Protons - positively charged and have a relative mass of 1
Neutrons - neutral and have a relative mass of 1
Electrons - negatively charged and have a relative mass if 1/1835 (negligible)
The nucleus of an atom contains protons and neutrons so is positively charged and where most of the mass is concentrated.
Atoms are neutral as they have the same number of protons and electrons.
The mass number of an atom is the number of protons and neutrons in the nucleus.
The atomic number of an atom is the number of protons in the nucleus of an atom.
The relative atomic mass of an element is its average mass of 1 atom of all its isotopes.
Relative Atomic Mass (Ar) = (Isotope 1 abundance X Isotope 1 mass) + (Isotope 2 abundance X Isotope 2Mass) / Sum of abundances