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Section 1: Physical Chemistry 1
2: Amount of substance
2.6 Balanced equations, atom economies & percentage yields
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Percentage atom economy
is:
Economic, ethical and environmental advantages for society and for industry of developing
chemical processes
with a high atom economy.
A compound will be
ionic
if
it contains a
metal
it's an
acid
in solution (will contain
H+
ions)
it's an
ammonium
salt (containing
NH4+
ions)
How do you know if an ion is positive or negative?
All
metals
form positive ions
Simple non-metals ions are negative
What happens when an ionic compound dissolves
Ions
separate
from eachother and become
surrounded
by
solvent
particles.
Group 1
ions
are
soluble.
Ammonium ion
,
NH4+
is
soluble
Nitrate
ions
NO3-
are
soluble
All
halide ions
are
soluble
, except
silver halides
,
AgX
and
lead (II) halides
PbX2
All
sulfate
ions are
soluble
, except
barium sulfate
,
calcium
sulfate and
lead (II) sulfate
All
carbonates
are
insoluble
, except
sodium carbonate
,
potassium carbonate
and
ammonium carbonate
All
hydroxides
are
insoluble
except
sodium
hydroxide
and
potassium
hydroxide
Remember than S.P.A.N. (
sodium
,
potassium
,
ammonium
or
nitrate-containing
) compounds are
always
soluble.
Writing
ionic equations
Wrtie down the
chemical equation
including state symbols
Rewrite by
separating
the
soluble
ionic compounds into their
dissociated
ions.
Cancel
out the
spectator ions
Write the
net ionic equation
A
precipitate
is a
solid
formed by the reaction of
two
aqueous
solutions.
Atom economy tells us how
efficient
a reaction is.
% atom economy = (
molecular
mass
of
desired
product
/
sum
of
Mr
of
all
reactants
)
x
100
Higher
atom economies are used in
industries
Better
for the
environment
Less
waste
to be
disposed
of
Efficient
use of
raw materials
so the process is
sustainable
Less
expensive
DO
USE
BALANCING
NUMBERS WHEN CALCULATING
%
ATOM ECONOMY
Percentage yield = (
actual
yield /
theoretical yield
)
x
100
Percentage yield = no. of
moles
of
product
obtained /
theoretical
max
no. of
moles