Hard Soft Acid Bases

Cards (15)

  • Hard Lewis Acid
    • H+
    • Li+
    • Na+
    • K+
    • Be2+
    • Mg2+
    • Ca2+
    • Al3+
    • Cr2+
    • Cr3+
    • Mn2+
    • Fe3+
    • Co3+
    • Ti4+
  • Borderline Lewis Acid
    • Fe2+
    • Co2+
    • Ni2+
    • Cu2+
    • Zn2+
    • Pb2+
  • Soft Lewis Acid
    • Cu+
    • Ag+
    • Au+
    • Cd2+
    • Hg22+
    • Hg2+
    • Hg+
    • Pd2+
    • Pt2+
    • Pt4+
    • Fe0
    • Ni0
  • Hard Lewis Bases
    • F-
    • OH-
    • H2O
    • O2-
    • O2-
    • ROH
    • RO-
    • R2O
    • CH3CO2-
  • Borderline Lewis Bases
    • Cl-
    • Br-
  • Soft Lewis Bases
    • H-
    • R-
    • I-
    • C2H4
    • NH3
    • RNH2
    • N2H4
    • NO2-
    • N3-
    • N2
    • SO32-
    • H2S
    • HS-
    • S2-
    • RSH
    • RS-
    • R2S
    • S2O32-
  • Other Lewis Bases
    • NO3-
    • ClO4-
    • CO32-
    • SO42-
    • PO43-
    • C6H5NH2
    • SCN-
    • Pyridine (C5H5N)
    • SCN-
    • CN-
    • RNC
    • CO
  • The donor atoms of the base are highlighted with underline
  • Hard acid
    • Small cations, not easily to polarized, high charged, low electronegativity for a metal
  • Hard base
    • Halides, oxoanions (high charge/oxidation state), ionic bonding dominant, very high electronegativity, small sized donor atom
  • Interaction between hard acid/base
    • Predominantly coulombic, ionic, dipole-dipole and electrostatic
  • Dipole–dipole interactions are electrostatic interactions between molecules which have permanent dipoles - partial charged (e.g., HCl-HCl)
  • Soft acid
    • Larger cations, easily to polarize, low charge, intermediate to high electronegativity
  • Electric polarizability is the relative tendency of a charge distribution, like the electron cloud of an atom or molecule, to be distorted from its normal shape by an external electric field
  • Soft base
    • Large size, intermediate to high electronegativity