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Cards (33)

  • This video is dedicated to AQA chemistry and covers the properties of period 3 elements and their oxides
  • Sodium is more reactive than magnesium as the amount of energy required to remove an electron from sodium is lower than to remove two electrons from magnesium
  • Sodium reacting with cold water
    1. Forms a ball
    2. Fizzes
    3. Produces hydrogen gas
    4. Produces an alkaline solution of sodium hydroxide
  • Magnesium reacting with water
    1. Forms a weak alkaline solution of magnesium hydroxide
    2. Reacts much faster with steam to form magnesium oxide and hydrogen
  • Period 3 elements react with oxygen to form oxides, except sulfur which can form sulfur dioxide (oxidation number +4) or sulfur trioxide (oxidation number +6)
  • Oxides formed by period 3 elements
    • Sodium oxide
    • Magnesium oxide
    • Aluminium oxide
    • Silicon dioxide
    • Phosphorus pentoxide
    • Sulfur dioxide
  • Sodium/magnesium reacting with air
    Forms their respective oxides quickly
  • Aluminium oxide reacting with air
    Reacts slowly, but faster if powdered
  • Phosphorus reacting with air
    Spontaneously combusts
  • Sulfur dioxide reacting with air
    Burns steadily in oxygen
  • Group 3 metal oxides
    • Form giant ionic lattices, have high melting points due to strong electrostatic forces
  • Magnesium oxide
    • Higher melting point than sodium oxide due to higher charge density of Mg2+ ions
  • Aluminium oxide
    • Slightly lower melting point than magnesium oxide due to some covalent character from distortion of electron cloud
  • Silicon dioxide
    • Has higher melting point than other non-metal oxides due to its macromolecular covalent structure
  • Phosphorus pentoxide, sulfur dioxide
    • Have lower melting points as they form simple molecular structures held by weak intermolecular forces
  • Ionic oxides
    Contain O2- ions that accept protons from water to form alkaline solutions
  • Sodium hydroxide
    A strong base that readily dissolves in water, giving a high pH
  • Ionic oxides
    Contain the O2- ion that accepts protons from water molecules when dissolved in solution, forming hydroxides
  • Ionic oxide + water
    1. Forms hydroxide
    2. Releases H+
  • Sodium hydroxide
    Strong base that readily dissolves in solution, resulting in high pH (12-14)
  • Magnesium hydroxide
    Weak base that does not dissolve well in water, resulting in moderate pH (9-10)
  • Ionic oxides form basic solutions
  • Simple covalent oxides
    Formed from non-metals like phosphorus and sulfur, form acidic solutions (pH 0-2)
  • Phosphorus pentoxide + water
    1. Forms phosphoric acid
    2. Dissociates into 3 H+ and PO4 2-
  • Sulfur dioxide + water
    1. Forms sulfurous acid
    2. Dissociates into 2 H+ and SO3 2-
  • Sulfur trioxide + water
    1. Forms sulfuric acid
    2. Dissociates into 2 H+ and SO4 2-
  • Sulfur forms two main oxide products: SO2 and SO3
  • Silicon dioxide
    Insoluble in water, reacts with bases to form salts
  • Aluminium oxide
    Amphoteric, can act as both an acid and a base
  • Aluminium oxide + base
    Forms aluminium salt, no water produced
  • Aluminium oxide + acid
    Forms aluminium salt + water
  • Acid + base → salt + water (general reaction)
  • Sulfur oxides are an exception, forming two different products (SO2 and SO3)