The branch of physical chemistry that deals with the relationships and conversions between heat and other forms of energy
EndothermicReaction
A chemical reaction that absorbs heat from its surroundings, resulting in a decrease in temperature
Exothermic Reaction
A chemical reaction that releases heat to its surroundings, resulting in an increase in temperature
Enthalpy
A measure of the total heat content of a system, symbolized as II
Heat Energy
The energy transferred between objects due to a temperature difference, typically measured in joules (J) or calories (cal)
Calorimetry
The science of measuring the heat of chemical reactions or physical changes
Hess'sLaw
It states that the total enthalpy change for a reaction is the same, regardless of whether the reaction occurs in one step or in a series of steps
Chemical Kinetics
The study of the rates of chemical reactions and the factors that affect them
Collision Theory
It explains how chemical reactions occur and why reaction rates differ for different reactions
Catalyst
A substance that speeds up a chemical reaction without being consumed in the process
Positive catalyst
A substance that facilitates chemical reactions by lowering the activation energy barrier
Negative catalyst
A substance that hinders reactions by raising the activation energy barrier
Rate Law
An equation that relates the rate of a chemical reaction to the concentrations of reactants
Spontaneous Process
A process that occurs naturally without the need for external intervention
Nonspontaneous Process
A process that does not occur naturally and requires external intervention to proceed
Entropy
A measure of the disorder or randomness of a system
SecondLawofThermodynamics
It states that the entropy of the universe tends to increase over time
Chemical Equilibrium
A state in which the rates of the forward and reverse reactions are equal, resulting in no net change in the concentrations of reactants and products
LeChatelier'sPrinciple
It states that if a system at equilibrium is disturbed by a change in temperature, pressure, or concentration, the system will shift its position to counteract the change and restore equilibrium
FirstLawofThermodynamics
Also known as the law of conservation of energy, it states that energy cannot be created or destroyed, only transferred or converted from one form to another