Chemrevise

• Lithium (Li) atom


  Atomic Number: 3, Atomic Symbol: Li, Mass Number: 7
• Atomic Number (Z)


  Number of protons in the nucleus
• Mass Number (A)


  Total number of protons and neutrons in the atom
• Number of neutrons


  A - Z
• Isotopes


  Atoms with the same number of protons, but different numbers of neutrons
• Relative isotopic mass


  Mass of one atom of an isotope compared to one twelfth of the mass of one atom of carbon-12
• Relative atomic mass


  Average mass of one atom compared to one twelfth of the mass of one atom of carbon-12
• Relative molecular mass


  Average mass of a molecule compared to one twelfth of the mass of one atom of carbon-12
• Isotopes have similar chemical properties because they have the same electronic structure. They may have slightly varying physical properties because they have different masses.
• Mass spectrometer


  • Can be used to determine all the isotopes present in a sample of an element and to therefore identify elements
  • Can measure m/z (mass/charge ratio) and abundance for each isotope
• Species for a peak in a mass spectrum

  • 24Mg+
  • 25Mg+
  • 26Mg+
• Calculating relative atomic mass

  1. R.A.M = (isotopic mass x % abundance) / 100

  2. R.A.M = (isotopic mass x relative abundance) / total relative abundance
• Mass spectra for Cl2 and Br2


  • Cl has two isotopes Cl35 (75%) and Cl37(25%)
  • Br has two isotopes Br79 (50%) and Br81(50%)
• Peaks in mass spectra for Cl2 and Br2

  • Cl35Cl35 +
  • Cl35Cl37 +
  • Cl37Cl37 +
  • Br79Br79 +
  • Br79Br81 +
  • Br81Br79 +
  • Br81Br81 +
• Sometimes two electrons may be removed from a particle forming a 2+ ion. 24Mg2+ with a 2+ charge would have a m/z of 12
• Molecular ion


  The peak with the largest m/z, due to the complete molecule and equal to the Mr of the molecule
• Mass spectrum for butane

  • Molecular ion C4H10+
  • Fragments at 43, 29
• First ionisation energy


  The energy required when one mole of gaseous atoms forms one mole of gaseous ions with a single positive charge
• Second ionisation energy


  The energy required when one mole of gaseous ions with a single positive charge forms one mole of gaseous ions with a double positive charge
• Factors affecting ionisation energy

  • Attraction of the nucleus
  • Distance of the electrons from the nucleus
  • Shielding of the attraction of the nucleus
• Successive ionisation energies are always larger
• Removing the first electron

  Positive ion is formed, increasing the attraction on the remaining electrons
• The pattern in the first ionisation energy gives us useful information about electronic structure
• Helium has the largest first ionisation energy
• Going down a group

  First ionisation energies decrease
• Going across a period

  First ionisation energies generally increase
• Sodium has a much lower first ionisation energy than Neon
• There is a small drop in first ionisation energy from Mg to Al
• n


  In the first shell closest to the nucleus and has no shielding effects from inner shells
• n has a bigger first ionisation energy than H


  As it has one more proton
• Phosphorus 1s2 2s2 2p6 3s2 3p3, Sulphur 1s2 2s2 2p6 3s2 3p4
• Two electrons of opposite spin in the same orbital
• An early model of the atom was the Bohr model (GCSE model) with electrons in spherical orbits. Early models of atomic structure predicted that atoms and ions with noble gas electron arrangements should be stable.
• The A-level model


  • Electrons are arranged on principle energy levels numbered 1,2,3,4.. with sub energy levels labelled s, p, d and f
  • s holds up to 2 electrons, p holds up to 6 electrons, d holds up to 10 electrons, f holds up to 14 electrons
• Orbitals represent the mathematical probabilities of finding an electron at any point within certain spatial distributions around the nucleus
• Each orbital has its own approximate, three dimensional shape. It is not possible to draw the shape of orbitals precisely.
• An atom fills up the sub shells in order of increasing energy (note 3d is higher in energy than 4s and so gets filled after the 4s)
• For oxygen 1s2 2s2 2p4
• Spin diagrams


  An arrow is one electron, the arrows going in the opposite direction represents the different spins of the electrons in the orbital, a box represents one orbital
• When filling up sub levels with several orbitals, fill each orbital singly before starting to pair up the electrons