ORGO 1 E3
Cards (24)
- Both SN1 and SN2 have intermediates
- Only SN1 doesn't have a transition-state
- E1 cannot happen with 1°
- Leaving group=electronegative
- Bulky base=E1
- NaOH= E2
- When the thing replacing your LG has the same priority (same row), need to switch dash to wedge
- Markovnikov= add H to the side with the most amount of H's
- E2 is a base dependent reaction
- Bulky base=least stable alkene
- Non-bulky base=most stable alkene
- SN1= charge so racemic
- E1= protic
- E2= protic
- SN1= protic
- SN2= aprotic
- BH3 & THF= Anti-Markovnikov
- O3= cutting through bond
- OsO4= 2 OH's
- DMS=H turns into OH
- How to turn OH into LG: OH + Ts-Cl = OTs
- X2= epoxide
- unstable=most likely leave
- Transition Metals= Ni, Pd, Pt, Rh, IrHow many wedges and dashes? 2 wedges
- (Os, Mn)O4 + H2O = 2 OH'sHow many wedges and dashes? 2 wedges
- When deciding which side gets X when the epoxide breaks off, it's 3°>2°>1°