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PAPER 1 - chemistry
Extracting metals and equilibria
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Reactivity series
Potassium
,
Sodium
, Calcium, magnesium highest
Gold, Silver, Copper, hydrogen lowest
metals at top of series are
less resistant
to
oxidation
so
corrode
easily
Potassium
,
sodium
and
ammonium
salts are
soluble
To maximise yield -
low temp
,
high pressure
low temp
means equilibrium shifts
exothermic
high pressure
means equilibrium shifts to
fewer molecules
Pressure
the molecules will move to the
side
with the
fewest
molecules as there is more
space.
Temperature
A
low
temperature means that the reaction will want to
heat
up the space, and go in the
exothermic
direction. Eg. will make more
ammonia
LeChateliers
principle
If we impose a
change
on a
system
, the
system
will react to
oppose
the
change
Exothermic - energy out
Endothermic - energy in
dynamic equilibrium
forward and
backward
reaction are happening at the same time and at the same rate, and the
concentrations
have reached a balance so wont change.