Mixtures are made of 2 or more substances (elements or compounds) that haven't been chemically combined. Mixtures can be separated. Their chemical properties don't change because they have been mixed with another substance.
Filtration
Separates mixtures of insoluble (can't dissolve) solids and liquids.
Done by pouring the mixture through filter paper:
The insoluble solid is trapped.
The liquid runs through the paper and is collected below.
Chromatography
Separates solutions with a number of different solutes (solids) in the solvent (liquid).
Place a drop of the solution to be separated near the bottom of a piece of chromatography paper. Dip the very bottom of the paper into a suitable solvent. The solvent (liquid) moves up the paper and carries the solutes (solids) in the solution with it.
Different solutes (solids) move at different speeds, so they separate on the paper.
Crystallisation
Separates solutions into their constituent (different) parts: dissolved solids (solutes) and liquids (solvents).
Heat the mixture so that the solvent evaporates.
Eventually, crystals of the solute (dissolved solids) will form.
We can collect the solvent (liquid) by condensing it as it evaporates.
In chromatography, the number of spots produced by a mixture can vary depending on which solvent is used.
The definition of a chemically pure substance is that it consists of only a single element or compound.
This means that pure samples will only ever produce 1 chromatography spot regardless of solvent identity.
A solvent (mobile phase) is run through the mixture on paper (contains the stationary phase). The substances will move up the paper at different rates. The most soluble substance will move the furthest.
Rf value
Rf = distance travelled by substance/ distance travelled by solvent.
What do we call a pure sample that's run next to the tested substance to see if it's a component in the mixture?
Reference substance
The elements are arranged in order of their atomic number (number of protons).
Elements in the same group have the same number of electrons in their outer shell
Because all elements in a group have the same number of electrons in their outer shell, they have similar chemical properties. This means they will all react in similar ways.
Transition metals have: higher melting points, higher density and lower reactivity.
Metallic bonding involves an attraction between positively charged ions and negatively charged, delocalised electrons.
Metallic bonds are found in metals and alloys (mixtures of metals and other substances).
Intramolecular forces are forces within molecules.
Small molecules have weakintermolecularforces. This means that they have lowmelting and boiling points.
Intramolecular bonds
Strong covalent bonds found within small molecules
Intermolecular forces Weak forces found between small molecules
The sum of intermolecular forces between smaller molecules is small
The sum of intermolecular forces between bigger molecules is greater
Small Covalent Molecules
Lower melting/ boiling points
Don't conduct electricity
Large Covalent molecules
Higher melting/ boiling points
Don't conduct electricity
Giant Covalent Structure
Some non-metals form giant structures with atoms joined together by covalent bonds.
Giant Covalent Structures
NoSpecificFormula
Giant covalent structures don't have a specificformula because the structure can be any size.
Giant Covalent Structures
Very high melting points
The strong covalent bonds between atoms make them solids at room temperature.
High temperatures and significant energy are required to break the structure's covalent bonds.
Giant Covalent Structures
1 large molecule
Giant covalent structures exist as 1 large structure or molecule.
There are no intermolecular forces because there is only 1 molecule.
Polymers are large, chain-like molecules that can extend for thousands of atoms. Polymers are held together by:
Strong covalent bonds between atoms in molecules.
Weak intermolecular forces between molecules.
Because of the large size of polymer molecules, the intermolecular forces add up to be quite strong.
Polymers are usually solid when at room temperature.
Many polymers melt easily because the intermolecular forces remain less strong than chemical bonds.
Polymers are made up of repeating units. Because of this, we can show their chemical structure as a unit that is repeated lots of times.
Giant covalent structures have very high melting points. This is because the covalent bonds between the atoms are very strong.
Diamond
High melting point
A lot of energy is needed to break strong covalent bonds.
Diamond has lots of strong covalent bonds. This means that it has a high melting point.
Diamond
Covalent Bonds
Each carbon atom in diamond is bonded to 4 other carbon atoms by strong covalent bonds.
This creates a giant covalent structure.
Diamond
Does not conduct electricity
Diamond does not conduct electricity because there are no delocalised electrons in the diamond structure.
Diamond
Hard
There are lots of strong covalent bonds in diamond. This makes it very hard.
Because diamond is hard, it is used as a cutting tool to cut other materials.
Graphite
Soft
The carbon atoms form layers of hexagonal (6-sided) rings, with weak intermolecular forces keeping the layers together.
The layers can easily slide over one another, so graphite is very soft.
This makes graphite useful as a lubricant and as pencil ‘lead’.
Graphite
Covalent Bonds
Each carbon atom in graphite is bonded to 3 other carbon atoms by strong covalent bonds.
This creates a giant covalent structure.
Graphite
Conducts Electricity
Each carbon atom forms 3 bonds.
This means that there is 1 delocalised electron from every carbon atom.
This electron can move freely, so graphite is a good electrical conductor.
How many other carbon atoms is each carbon atom in diamond bonded to?
Four
Diamond cannot conduct electricity as there are no delocalised electrons in its structure.
Graphene
Conducts Electricity
Each carbon atom has a delocalised electron.
Graphene is a single layer of graphite so it also conducts electricity because of the carbon atoms’ delocalised electrons.