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mod 5
5.3.1 transition metals
Precipitation reactions with sodium hydroxide and ammonia
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Precipitation reactions with
sodium
hydroxide
and
ammonia
[Cu(H2O)6 ]2+
blue
solution forms
blue
ppt
[Mn(H2O)6 ]2+
very pale pink
solution forms
pale
brown
ppt
[Fe(H2O)6 ]2+ (aq)
green
solution make
green
ppt
[Fe(H2O)6 ]3+
yellow
/
brown
solution forms
brown
ppt
[Cr(H2O)6 ]3+
green
solution form
green
ppt
With
ammonia
when added in limited amounts the
same
hydroxide precipitates form.
The ammonia acts as a
base
, removes a proton from the aqueous complex and becomes the ammonium
ion