• There are three states of matter, namely solids, liquids, and gases.
• All states of matter differ in their properties based on the arrangement of their particles.
Solid
-rigid
-fixed shape
-fixed volume
-cannot be squashed
Liquid
-not rigid
-no fixed shape
-fixed volume
-cannot be squashed
Gas
-not rigid
-no fixed shape
-no fixed volume
-can be squashed
PROPERTIES OF GASES
-Gas is the state of matter that has particles that are freely moving and are far from each other which makes them, "highly compressible"
Gases have important fundamental properties that are measurable:
-Volume
-Pressure
-Temperature
-Amount of the gas or the number of moles.
Volume
-It is the amount of space occupied by a gas sample.
Its Sl unit is in liters (L)
milliliters (mL)
cubic centimeter (cm3)
cubic meter (m3)
cubic decimeter (dm3)
Pressure
-Pressure of the gas is the force exerted by the gas per unit area.
-The SI unit used for pressure is pascal (Pa), named after Blaise Pascal.
Other units of pressure are:
-atmosphere (atm)
-millimeter of mercury (mmHg)
-Torr
-kilopascal (kPa)
-pounds per square inch (psi)
Temperature
-The temperature of a gas depends. on its kinetic energy.
-Gases expand when the temperature is increased.
The temperature of gas is expressed in:
-Fahrenheit (°F)
-Centigrade or Celsius (°C) and
-Kelvin (K)
Though we often use the Celsius degree when dealing with temperature involving involving gases, we always express it in Kelvin temperature.
The unit Kelvin was named after Lord Kelvin, a Scottish physicist who has identified the lowest attainable temperature known as absolute zero with a value of -273°C.
To convert Celsius to Kelvin, we use the equation K = °C + 273.15
Amount of Number of Moles
-The mass of the gas is related to its number of moles and is generally expressed in kilogram (kg) or gram (g).
Equation: Number of moles = mass of the gas/molar mass of the gas
In symbols, n = m/M
KINETIC MOLECULAR THEORY OF GAS
-The properties of gases can explained in terms of their molecular motion.
-The ideas about molecular motion were developed into the kinetic molecular theory by Rudolf Clausius, James Maxwell, and Ludwig Boltzman.
KINETIC MOLECULAR THEORY OF GAS Their postulates on the behavior of gases are:
A gas consists of very small particles. The particles are in constant, random, and straight- line motion.
2. The particles of a separated by distances much larger than their size.
3. The gas particles collide with each other and with the walls of the container in a perfectly elastic manner.
4. The average kinetic energy of the gas particles is proportional to the absolute (Kelvin) temperature. As the temperature increases, the gas particles move faster.
BOYLE'S LAW
-at constant temperature, the volume of the gas increases as the pressure decreases. The volume of the gas decreases and the pressure increases.
Formula for Boyle's Law
P1V1 = P2V2
CHARLES' LAW
-French Chemist Jacques Charles discovered that the volume of a gas at constant pressure changes with temperature.
CHARLES' LAW
-From his experiment on balloons, Charles observed that, at constant pressure, the volume of gas increases with every increase in temperature. Also, volume decreases as temperature decreases.
Charles' Law states that the volume of a gas is directly proportional to the absolute temperature provided the pressure remains constant.
CHARLES' LAW
If the temperature of a gas increases, the volume increases. If the temperature decreases, the volume of a gas decreases.
Mathematical equation of a Charles' Law:
V1/T1=V2/T2
V1 = Initial Volume
V2= Final Volume
T1 = Initial Temperature
T2= Final Temperature
CHARLES' LAW
The temperature must be the Absolute temperature expressed in a "Kelvin (K)" scale. °C+ 273.15
JOSEPH LOUIS GAY-LUSSAC
-The person who who is credited with the determination of the temperature-pressure relationship in gases at constant volume.
JOSEPH LOUIS GAY-LUSSAC
-He deduced that the pressure of the gas is directly proportional to its temperature.
GAY-LUSSAC'S LAW
When the temperature of gases increases, its pressure also increases or vice versa.
GAY-LUSSAC'S LAW
-At constant volume, the pressure of a fixed mass of gas is directly proportional to the absolute temperature.
GAY-LUSSAC'S LAW EQUATION
P1/T1 = P2/T2
P1=Initial Pressure
P2=Final Pressure
T1=Initial Temperature
T2=Final Temperature
COMBINED GAS LAW
-Boyle's Law and Charles' Law can be combined and treated as a single law, called the combined gas law, which describes the pressure-volume- temperature relationship of α constant amount of gas.
COMBINED GAS LAW
-The pressure and volume of a gas are inversely proportional to each other, but are both directly proportional to the temperature of that gas.