protons and neutrons giving an overall positive charge
What is the relative charge of P, E, N?
P = +1
N = 0
E = -1
What is the relative mass of P, E, N?
P = 1
E = 1/1840
N = 1
What’s an ion?
When an atom loses or gains an electron. This means its no longer neutral and will have an overall charge
What’s an isotope?
Atoms of the same element with the same atomic number but a different number of neutrons so different mass number
What’s relative atomic mass?
The mean mass of an atom of an element, relative to 1/12 of the mean of an atom of the carbon-12 isotope
What’s the isotopic mass?
The mass of an isotope relative to 1/12 of the mean mass of an atom of the carbon-12 isotope
What’s relative molecular mass?
The meanmass of a molecule of a compound, relative to 1/12 of the mean mass of an atom of the carbo-12 isotope
What’s a mole?
Unit of measurement for substances
What is avogadros constant?
6.02 x 10^23
What is molar mass?
Mass per mole and has units g mol-1
What’s molar gas volume?
the gas volume per mile and has units dm3 mol-1
What is the empirical formula?
the simplest whole number ratio of atoms of each element present in a compound
Water of Crystallisation is water that is part of the crystalline structure. The molecules stoichiometrically chemically bonded into the crystal structure
An anhydrous substance contains no water of crystallisation
Hydrated substance fountains water of crystallisation
What is the
formula for % yield
% yield = Experimental mass/theoretical mass x100
What’s the formula for percentage composition?
% composition = Mr of element/Mr of compound X100
How do you calculate concentration?
Number of moles/Volume
What is the formula for concentration (g dm-3)?
Mass/Volume
What are the maximum electrons that can be held in the first 4 orbitals (s,p,d,f)?
2, 6, 10, 14
What happens in a fusion reaction?
Two lighter nuclei join to give a single heavier nucleus. Required high temp and pressure
What is ionic bonding?
An electrostatic attraction between positive and negative ions
Between what atoms do ionic bonding occur?
metals and non metals. transferred from metal to non metal to achieve full outer shells
When the electrons are transferred it creates charged particles called ions. Oppositely charged ions attract through electrostatic forces to form a giant ionic lattice.
What is a covalent bond?
the string electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms between 2 metals
What’s a dative covalent bond?
When both of the electrons in the shared pair are supplied from a single atom. This is indicated using an arrow from the lone electron pair
Simple covalent
consist of covalently bonded molecules held together with intermolecular forces. Shape is determined by the number of electron pairs around the central atom and repulsion between them. Each pair naturally repel each other so the largest bond angle possible exists
Lone pair repulsion
Any lone pairs around the central atom provide additional repulsive forces. For every lone pair present the bond angle between covalent bonds is reduced by 2.5°
What is the bond length?
The average distance between two nuclei in a covalent bond
What is a bond angle?
The angle between two covalent bonds from the same atom
Bond angles and naming
-
Bond angles and naming
-
Giant covalent structures
Macro molecular covalent substances are covalently bonded into a giant lattice structure. Each atom has multiple covalent bonds which are very strong giving the substance a very high melting point
Diamond
A macro molecular structure made up of carbon atoms each bonded to four further carbons. This forms a rigid tetrahedral structure making it one of the hardest strongest materials
Graphite
Another macromolecular structure made of carbon atoms. However in graphite each carbon is bonded to 3 others in flat hexagonal sheets. Only 1 delocalised electron per carbon atom. These can move freely allowing graphite to conduct electricity. Therefore it can be used in an electrode. The intermolecular forces are weak and can slide meaning it’s a lubricant
Metallic bonding
Consists of a giant lattice of positively charged ions surrounded by a sea of delocalised electrons. Very strong electrostatic forces of attraction between oppositely charged particles.
The greater the charge on +ve the stronger the attractive force since more electrons r released
Larger ions produce a weaker attraction bc greater atomic radius
Metallic structure
Good conductors. Delocalised electrons able to move and carry a flow. Malleable because uniform layers of positive ions are able to slide over one another. Delocalised electrons prevent fragmentation as they can move around lattice
Metallic structure
Electrostatic forces between +ve ions and delocalised electrons are v strong and therefore require a lot of energy to overcome. High melting points and nearly always solid at room temp. Mercury is the only exception as it’s liquid
What order is the period table have elements in?
increasing proton number
All elements in a period have the same number of shells