In liquid form the covalent molecules would vibrate and move from place to place. The atoms in each molecule are held together by very strong covalent bonds There are very weak intermolecular forces between molecules. As we increase the temperatures the molecules increase in vibrations and at a certain point this vibration is strong enough to break the weak intermolecular forces holding the molecules to each other. The molecules boil and turn to a gas at this point. Not a lot of energy is required to break these intermolecular forces