Substances in which 2 or more elements are chemicallycombined
Types of strong chemical bonds
Ionic
Covalent
Metallic
Ionic bonding
Particles are oppositelychargedions
Occurs in compounds formed from metals combined with non-metals
Covalent bonding
Particles are atoms which share pairs of electrons
Occurs in most non-metallic elements and in compounds of non-metals
Metallic bonding
Particles are atoms which share delocalised electrons
Occurs in metallic elements and alloys
Formation of ionic compounds
1. Metal atoms lose electrons to become positively charged ions
2. Non-metal atoms gain electrons to become negatively charged ions
An ion is an atom that has lost or gainedelectron(s)
Ions produced by metals in Groups 1 and 2 and by non-metals in Groups 6 and 7 gain full outer shell of electrons, so they have the same electronic structure as a noble gas (Group 0 element)
Electron transfer during the formation of an ionic compound
Dotandcross diagram (e.g. for NaCl)
Covalent bonding
Atoms share one or more pairs of electrons
Substances with covalent bonds
HCl
H2
O2
Cl2
NH3
CH4
Polymers
Large covalentlybonded molecules
Giant covalent structures (macromolecules)
Many atoms covalently bonded in a lattice structure
Examples of giant covalent structures
Diamond
Silicon dioxide
Metallic bonding
Positive ions (atoms that have lost electron(s)) and delocalised electrons arranged in a regular pattern
Delocalised electrons in metallic bonding
Free to move through the structure
Shared through the structure, making metallic bonds strong
Ions
Charged particles that can be single atoms or groups of atoms, formed when electrons are lost or gained
Metal atoms lose electrons to form positive ions, non-metal atoms gain electrons to form negative ions
Stable electronic structure
Having a full outer shell of electrons, like a noble gas
Periodic table group number and ionic charge
Group 1 elements form 1+ ions
Group 2 elements form 2+ ions
Group 6 elements form 2- ions
Group 7 elements form 1- ions
Ionic bonding
When metals react with non-metals, electrons are transferred from the metal atoms to the non-metal atoms, forming oppositely charged ions that are strongly attracted to each other
Dot and cross diagrams
Used to show what happens during ionic bonding, with electrons represented by dots and crosses
Giant ionic lattice
The structure of ionic compounds, a closely-packed regular arrangement of oppositelycharged ions held together by strong electrostatic forces
Representations of ionic compounds
Dot and cross diagrams
3D models
Ball and stick models
Working out the formula of an ionic compound
1. From a dot and cross diagram: count the atoms of each element
2. From a 3D or ball and stick model: identify the ions and balance the charges
Properties of ionic compounds
High melting and boiling points due to strong electrostatic attraction
Most dissolve easily in water
Ionic compounds have high melting and boiling points, and most dissolve easily in water
Electrical conductivity
Ionic compounds don't conduct electricity when solid because the ions are all held in fixed positions. However, when they're melted or dissolved, the ions are free to move and they'll carry electric charge.
Dissolving in water
Free ions
Covalent Bonding
Atoms sharing their electrons
Covalent bond
A pair of electrons is shared between two atoms. Atoms share electrons with each other to get full outer shells (highest energy levels). They only share electrons in their outer shells and both atoms involved in the bond end up with one extra electron in their outer shell. The positively charged nuclei of the bonded atoms are attracted to the shared pair of electrons by electrostatic forces, making covalent bonds very strong.
Single covalent bond
Provides one extra shared electron for each atom
Covalent bonds
Occur between non-metal atoms, either in non-metallic elements or in compounds of non-metals
Representing covalent bonding
Dot and cross diagrams
Displayed formulas
3D models and ball and stick models
Dot and cross diagrams
The shared electrons can be drawn in the overlap between the outer orbitals of the two atoms
Displayed formulas
Show the covalent bonds as single lines between atoms
3D models and ball and stick models
Show the atoms and their arrangement in space
Finding molecular formulas
Count up how many atoms of each element there are in a diagram of the molecule
Simple molecules
Made up of only a few atoms joined by covalent bonds
Chlorine
Chlorine atoms need one more electron to gain a stable electronic structure. So, two chlorine atoms each share one of their electrons to form a chlorine molecule containing one shared pair of electrons - a single covalent bond.