Density is the mass of a given volume of a substance
Density
Determined by the mass of the atoms it is made from and how closely these atoms are packed together
Substance densities
Water (l): 1 000 kg/m3
Glass (s): 3 140 kg/m3
Iron (s): 7 700 kg/m3
Aluminium (s): 2 800 kg/m3
Hydrogen (g): 0.085 kg/m3
Density
Solids have particles packed close together
Liquids have particles free to move so the same mass takes up more space
Gases have particles taking up a much greater volume than liquids and solids
For any particular substance, a solid is usually denser than its liquid and the liquid is usually denser than the gas
Solid water (ice) is less dense than liquid water, which is why ice floats on water
Finding the density of an irregular object
1. Place object in known volume of water and measure amount of water displaced, which equals the volume of the object
2. Then calculate density using mass and volume
A change of state can be brought about by changing the temperature or pressure of a material
Mass is conserved when a substance changes state, only the volume changes
Changes of state are physical changes, not chemical changes
Physical changes can be reversed, chemical changes cannot
Changes of state
Melting
Evaporating
Deposition
Subliming
Condensing
Freezing
Determining volume of irregular object
Place object in known volume of water and measure amount of water displaced, which equals the volume of the object
Internal energy is the energy stored in a system by the atoms and molecules that make up that system
Internal energy
Total kinetic and potential energy of particles in a system
When heat is added to a system, the internal energy of the particles increases, which can result in the material changing state
Specific heat capacity (c)
Energy required to raise the temperature of 1 kg of a substance by 1°C
Latent heat
Energy needed to change the state of a substance without a change in temperature
Specific latent heat of fusion (Lf)
Latent heat for melting
Specific latent heat of vaporisation (Lv)
Latent heat for evaporating
As heat energy is added, temperature rises until melting point, then all energy goes to changing state with no temperature change, then temperature rises again until boiling point
Internal energy
The total kinetic and potential energy of all the particles within a system
Changing the internal energy of a stone
Heating it
Water and isooctane both boil at 100 °C, but isooctane boils first when the same mass of each is placed on a heater
Reason why isooctane boils first
Isooctane has a lower specific heat capacity than water so less heat energy is needed to raise its temperature to its boiling point
Calculating temperature rise of water
1. ΔE = m c Δθ
2. Δθ = ΔE / (m x c)
3. Δθ = 25 200 / (0.2 x 4200) = 30 °C
Latent heat
The energy needed to change the state of a substance without changing the temperature
Latent heat of fusion
The energy needed to change between solid and liquid
Latent heat of vaporisation
The energy needed to change between liquid and gas
Calculating heat energy needed to melt a 250 g candle
1. E = m Lf
2. E = 0.25 x 200 000 = 50 000 J
Brownian motion
Constant random motion of molecules in a gas
Temperature of a gas
Related to the average kinetic energy of the particles
Increasing temperature of a gas
Particles move faster
Faster moving gas particles
Exert greater force on container walls
Heating a sealed can of air
Air molecules move faster, increasing pressure on can walls
Gas pressure is directly related to temperature if volume remains constant
Pressure in a gas
Caused by collisions of gas particles on container walls
Compressing a gas in a fixed container
More particles in a given volume, increasing pressure on walls